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• W4384346739 startingPage "65" @default.
• W4384346739 abstract "The reaction kinetics of hydrogen combustion was intensively studied already in the first half of the 20th century. The first, second and third explosion limits were discovered, and mechanistic explanations were given. However, fine details of the reaction mechanism and the exact rate parameters are still not known. New reaction steps were proposed even in the last few years. The explosive—non-explosive regions are separated by an inverted S-shape curve in the T − p plane. The backbone of the curve is approximately equal to the line where the rates of reactions H + O2 → OH + O and H + O2 + M → HO2 + M are equal. The regions of strong and weak explosions are below and above the backbone line, and these regions are dominated by H/O/OH and HO2/H2O2 catalytic cycles, respectively. In a small vessel, the adsorption of radicals HO2 and H form the upper and lower branches of the curve, respectively. All qualitative features of the hydrogen combustion system can be explained by a 10-step mechanism. Several web sites are recommended here which contain comprehensive collections of recent hydrogen combustion mechanisms, direct and indirect experimental data, and theoretical determinations." @default.
• W4384346739 created "2023-07-15" @default.
• W4384346739 creator A5026884101 @default.
• W4384346739 date "2023-01-01" @default.
• W4384346739 modified "2023-10-01" @default.
• W4384346739 title "Reaction Kinetics of Hydrogen Combustion" @default.
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• W4384346739 doi "https://doi.org/10.1007/978-3-031-28412-0_2" @default.
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