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• W4384563784 endingPage "136233" @default.
• W4384563784 startingPage "136233" @default.
• W4384563784 abstract "The novel 6-ethyl-3-{[(3-cyano-4,6-dimethyl-2-oxo-1,2-dihydropyridin-1-yl)imino] methyl}-4H-pyrano[3,2-c]quinoline-4,5(6H)-dione (EPIMPQ) was obtained by reacting pyrano[3,2-c]quinoline-3-carboxaldehyde (1) with 1-amino-4,6-dimethyl-2-oxo-1,2-dihydropyridine-3-carbonitrile (2). For the first time, the EPIMPQ thin films were produced using simple, easy, and efficient thermal evaporation under a vacuum. Based on its correct elemental analysis and spectrum data, the structure of EPIMPQ was inferred using FTIR, 1H NMR, 13C NMR, and mass spectra. Density Functional Theory (DFT/B3LYP) methods using the 6–311++G(d,p) basis set were used to achieve the optimized molecular structure and the related geometrical parameters. The molecular electrostatic potential (MEP), chemical activity characteristics, and non-linear optical (NLO) properties have also been investigated. Optical spectroscopy was used to determine the optical band gap and other dispersion parameters of the films, which was vital in the development of photodiode devices. The optical band transitions of EPIMPQ were investigated, and the direct optical gap was determined to be 2.75 eV and 3.06 eV. Furthermore, the current-voltage (J-V) characteristics of EPIMPQ film-based devices under the illumination of 80 mW/cm2 show that as the reverse bias is increased, the photoresponsivity of EPIMPQ film-based devices increases. The attractive phototransient features of the produced devices show that they can be employed as photodiode devices." @default.
• W4384563784 created "2023-07-18" @default.
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• W4384563784 date "2023-12-01" @default.
• W4384563784 modified "2023-09-27" @default.
• W4384563784 title "A new hybrid structure based Pyranoquinoline-Pyridine derivative: Synthesis, optical properties, theoretical analysis, and photodiode applications" @default.
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• W4384563784 doi "https://doi.org/10.1016/j.molstruc.2023.136233" @default.
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