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- W4384625935 abstract "Spinel-structured ordered-LiNi0.5Mn1.5O4 (o-LNMO) has experienced a resurgence of interest in the context of reducing scarce elements such as cobalt from the lithium-ion batteries. O-LNMO undergoes two two-phase reactions at slow rates. However, it is not known if such phenomenon also applies at fast rates. Herein, we investigate the rate-dependent phase transition behavior of o-LNMO through in operando time-resolved X-ray diffraction. The results indicate that a narrow region of the solid solution reaction exists for charge and discharge at both slow and fast rates. The overall phase transition is highly asymmetric at fast rates. During fast charge, it is a particle-by-particle mechanism resulting from an asynchronized reaction among the particles. During fast discharge, it is likely a core–shell mechanism involving transition from Li0+xNi0.5Mn1.5O4 to Li1+xNi0.5Mn1.5O4 in the outer layer of particles. The Li0.5Ni0.5Mn1.5O4 phase is suppressed during fast discharge and appears only through Li redistribution upon relaxation." @default.
- W4384625935 created "2023-07-19" @default.
- W4384625935 creator A5001764707 @default.
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- W4384625935 date "2023-07-18" @default.
- W4384625935 modified "2023-09-23" @default.
- W4384625935 title "Asymmetric Lithium Extraction and Insertion in High Voltage Spinel at Fast Rate" @default.
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- W4384625935 doi "https://doi.org/10.1021/acs.nanolett.3c02042" @default.
- W4384625935 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37462326" @default.
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