Matches in SemOpenAlex for { <https://semopenalex.org/work/W4384694310> ?p ?o ?g. }
- W4384694310 abstract "Abstract Catalytic enantioselective intermolecular C−H silylation offers an efficient approach for the rapid construction of chiral organosilicon compounds, but remains a significant challenge. Herein, a new type of chiral silyl ligand is developed, which enables the first iridium‐catalyzed atroposelective intermolecular C−H silylation reaction of 2‐arylisoquinolines. This protocol features mild reaction conditions, high atom economy, and remarkable yield with excellent stereoselectivity (up to 99 % yield, 99 % ee ), delivering enantioenriched axially chiral silane platform molecules with facile convertibility. Key to the success of this unprecedented transformation relies on a novel chiral PSiSi‐ligand, which facilitates the intermolecular C−H silylation process with perfect chem‐, regio‐ and stereo‐control via a multi‐coordinated silyl iridium complex." @default.
- W4384694310 created "2023-07-20" @default.
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- W4384694310 creator A5088144354 @default.
- W4384694310 date "2023-07-28" @default.
- W4384694310 modified "2023-09-23" @default.
- W4384694310 title "Chiral PSiSi‐Ligand Enabled Iridium‐Catalyzed Atroposelective Intermolecular C−H Silylation" @default.
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- W4384694310 doi "https://doi.org/10.1002/ange.202307812" @default.
- W4384694310 hasPublicationYear "2023" @default.
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