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- W4384697107 abstract "Abstract Deep geological repository is widely considered as the preferred solution for the final disposal of high-level radioactive waste. Investigation representative of the Hungarian disposal concept was conducted using mock-up diffusion cells to study the chemical changes of S235JR carbon canister and CEM II/B PURAM concrete under anerobic and water saturated conditions at 80°C. Micro-Raman, SEM-EDX, fluid and potentiometric analysis were performed over a period of 12 months. The discussion was supported by thermodynamic and reactive transport modeling. The findings revealed that a uniform corrosion process occurred, leading to rapid passivation of the C-steel with magnetite as the primary corrosion product. Modeling demonstrated that the increase in temperature to 80°C and the chemical evolution of the concrete did not significantly affect the corrosion passivation process. Although the formation of Fe-siliceous hydrogarnets is thermodynamically possible at 80°C, it did not jeopardize magnetite passivation. Overall, the results suggest that the containers would have a long lifespan under the studied disposal conditions." @default.
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- W4384697107 date "2023-07-18" @default.
- W4384697107 modified "2023-09-23" @default.
- W4384697107 title "Interactions between C-steel and blended-cement in concrete under radwaste repository conditions at 80 °C" @default.
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- W4384697107 doi "https://doi.org/10.21203/rs.3.rs-3149550/v1" @default.
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