FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4384788578> ?p ?o ?g. }

• W4384788578 endingPage "15248" @default.
• W4384788578 startingPage "15238" @default.
• W4384788578 abstract "Heterostructure interfacial engineering between photocatalyst and co-catalyst to obtain an optimized electronic structure is a promising approach to improving their performance in the photocatalytic hydrogen evolution reaction (HER). In this work, two-dimensional nanopetal-like ZnIn2S4 (ZIS) with an adequately exposed active (110) edge facet-decorated Ni cluster heterostructure was prepared via chemical bath deposition, followed by photodeposition. In the catalyst preparation, the ZIS microstructure was modulated to sufficiently expose the active sites of the (110) edge for the HER, on which spontaneous interfacial engineering with an additional Ni cluster co-catalyst would be triggered via photodeposition in situ. The hydrogen production rate of the composite photocatalyst was excellent, at up to 26.80 mmol g-1 h-1 under simulated sunlight, which was 15.4 times greater than that of pristine ZIS. The optimized photocatalyst achieved a state-of-the-art apparent quantum yield of 61.68% at a single wavelength of 420 nm. Combined with systematic experimental characterization and density functional theory calculation, it was demonstrated that the separation and migration of charge carriers were significantly enhanced via the Ni cluster-induced interfacial electron redistribution, which contributed to the near-zero Gibbs free energy barrier and favored intermediate (*H) adsorption and desorption behavior, resulting in the superior photocatalytic performance. In summary, this work enables tuning of the interfacial electronic properties via spontaneous photodeposition of metallic cluster co-catalyst on the edge active sites, through which the separation of photogenerated charge carriers and surface redox reactions can be synergistically facilitated." @default.
• W4384788578 created "2023-07-20" @default.
• W4384788578 creator A5002851632 @default.
• W4384788578 creator A5009018022 @default.
• W4384788578 creator A5013238849 @default.
• W4384788578 creator A5023546714 @default.
• W4384788578 creator A5029861454 @default.
• W4384788578 creator A5057176376 @default.
• W4384788578 creator A5074942308 @default.
• W4384788578 date "2023-01-01" @default.
• W4384788578 modified "2023-10-14" @default.
• W4384788578 title "Interfacial Electron Modulation of 2D Nanopetal ZnIn2S4 with Edge-decorated Ni Clusters for Accelerated Photocatalytic H2 Evolution" @default.
• W4384788578 cites W1970127494 @default.
• W4384788578 cites W1976069553 @default.
• W4384788578 cites W1981756390 @default.
• W4384788578 cites W2000369435 @default.
• W4384788578 cites W2015639040 @default.
• W4384788578 cites W2040212495 @default.
• W4384788578 cites W2042492216 @default.
• W4384788578 cites W2043695984 @default.
• W4384788578 cites W2047334717 @default.
• W4384788578 cites W2057662683 @default.
• W4384788578 cites W2093337077 @default.
• W4384788578 cites W2094642361 @default.
• W4384788578 cites W2147055288 @default.
• W4384788578 cites W2501345610 @default.
• W4384788578 cites W2559507144 @default.
• W4384788578 cites W2584283542 @default.
• W4384788578 cites W2759147296 @default.
• W4384788578 cites W2776187611 @default.
• W4384788578 cites W2781636403 @default.
• W4384788578 cites W2899228857 @default.
• W4384788578 cites W2905837468 @default.
• W4384788578 cites W2906581948 @default.
• W4384788578 cites W2913985424 @default.
• W4384788578 cites W2920236064 @default.
• W4384788578 cites W2921096262 @default.
• W4384788578 cites W2921348471 @default.
• W4384788578 cites W2940692781 @default.
• W4384788578 cites W2942550896 @default.
• W4384788578 cites W2948096633 @default.
• W4384788578 cites W2971521778 @default.
• W4384788578 cites W2999014124 @default.
• W4384788578 cites W3005461540 @default.
• W4384788578 cites W3008580165 @default.
• W4384788578 cites W3012063396 @default.
• W4384788578 cites W3014276020 @default.
• W4384788578 cites W3036037066 @default.
• W4384788578 cites W3036061066 @default.
• W4384788578 cites W3041717223 @default.
• W4384788578 cites W3119464696 @default.
• W4384788578 cites W3133504200 @default.
• W4384788578 cites W3195474908 @default.
• W4384788578 cites W3196411394 @default.
• W4384788578 cites W3201913970 @default.
• W4384788578 cites W4206466961 @default.
• W4384788578 cites W4220676655 @default.
• W4384788578 cites W4220987024 @default.
• W4384788578 cites W4224239228 @default.
• W4384788578 cites W4282561510 @default.
• W4384788578 cites W4285607064 @default.
• W4384788578 cites W4289593668 @default.
• W4384788578 doi "https://doi.org/10.1039/d3nr02263c" @default.
• W4384788578 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37672041" @default.
• W4384788578 hasPublicationYear "2023" @default.
• W4384788578 type Work @default.
• W4384788578 citedByCount "0" @default.
• W4384788578 crossrefType "journal-article" @default.
• W4384788578 hasAuthorship W4384788578A5002851632 @default.
• W4384788578 hasAuthorship W4384788578A5009018022 @default.
• W4384788578 hasAuthorship W4384788578A5013238849 @default.
• W4384788578 hasAuthorship W4384788578A5023546714 @default.
• W4384788578 hasAuthorship W4384788578A5029861454 @default.
• W4384788578 hasAuthorship W4384788578A5057176376 @default.
• W4384788578 hasAuthorship W4384788578A5074942308 @default.
• W4384788578 hasConcept C104232198 @default.
• W4384788578 hasConcept C127413603 @default.
• W4384788578 hasConcept C147597530 @default.
• W4384788578 hasConcept C147789679 @default.
• W4384788578 hasConcept C150394285 @default.
• W4384788578 hasConcept C152365726 @default.
• W4384788578 hasConcept C159467904 @default.
• W4384788578 hasConcept C161790260 @default.
• W4384788578 hasConcept C164866538 @default.
• W4384788578 hasConcept C171250308 @default.
• W4384788578 hasConcept C17744445 @default.
• W4384788578 hasConcept C178790620 @default.
• W4384788578 hasConcept C185592680 @default.
• W4384788578 hasConcept C191897082 @default.
• W4384788578 hasConcept C192562407 @default.
• W4384788578 hasConcept C199360897 @default.
• W4384788578 hasConcept C199539241 @default.
• W4384788578 hasConcept C41008148 @default.
• W4384788578 hasConcept C42360764 @default.
• W4384788578 hasConcept C49040817 @default.
• W4384788578 hasConcept C55904794 @default.
• W4384788578 hasConcept C65165184 @default.
• W4384788578 hasConcept C74080474 @default.

• next