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• W4384926528 endingPage "306" @default.
• W4384926528 startingPage "302" @default.
• W4384926528 abstract "All fluorochemicals-including elemental fluorine and nucleophilic, electrophilic, and radical fluorinating reagents-are prepared from hydrogen fluoride (HF). This highly toxic and corrosive gas is produced by the reaction of acid-grade fluorspar (>97% CaF2) with sulfuric acid under harsh conditions. The use of fluorspar to produce fluorochemicals via a process that bypasses HF is highly desirable but remains an unsolved problem because of the prohibitive insolubility of CaF2. Inspired by calcium phosphate biomineralization, we herein disclose a protocol of treating acid-grade fluorspar with dipotassium hydrogen phosphate (K2HPO4) under mechanochemical conditions. The process affords a solid composed of crystalline K3(HPO4)F and K2-xCay(PO3F)a(PO4)b, which is found suitable for forging sulfur-fluorine and carbon-fluorine bonds." @default.
• W4384926528 created "2023-07-22" @default.
• W4384926528 creator A5007266295 @default.
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• W4384926528 creator A5071527287 @default.
• W4384926528 date "2023-07-21" @default.
• W4384926528 modified "2023-10-12" @default.
• W4384926528 title "Fluorochemicals from fluorspar via a phosphate-enabled mechanochemical process that bypasses HF" @default.
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