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• W4384927205 abstract "Intermetallic Nb3Sn alloys have long been believed to form through Sn diffusion into Nb. However, our observations of significant oxygen content in Nb3Sn prompted an investigation of alternative formation mechanisms. Through experiments involving different oxide interfaces (clean HF-treated, native oxidized, and anodized), we demonstrate a thermodynamic route that fundamentally challenges the conventional Sn diffusion mechanism for Nb3Sn nucleation. Our results highlight the critical involvement of a SnOx intermediate phase. This new nucleation mechanism identifies the principles for growth optimization and new synthesis of high-quality Nb3Sn superconductors." @default.
• W4384927205 created "2023-07-22" @default.
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• W4384927205 date "2023-07-01" @default.
• W4384927205 modified "2023-10-01" @default.
• W4384927205 title "Thermodynamic route of Nb3Sn nucleation: Role of oxygen" @default.
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• W4384927205 doi "https://doi.org/10.1063/5.0157659" @default.
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