Matches in SemOpenAlex for { <https://semopenalex.org/work/W4384938624> ?p ?o ?g. }
- W4384938624 endingPage "111557" @default.
- W4384938624 startingPage "111557" @default.
- W4384938624 abstract "Methyl N22-methyl-pyropheophorbides possessing various substituents at the C3-position were prepared by modifying natural chlorophyll-a. Their syntheses were based on the regioselective N22-methylation of a chlorin π-system and/or the functionalization of the C3-substituents in the resulting N22-methyl-chlorins. The synthetic N22-methyl-chlorins were obtained as cationic species due to their high basicity. The N22-methylation largely affected the ultraviolet–visible absorption and fluorescence emission spectra and especially moved the Qy absorption and intense emission maxima to shorter wavelengths and the Qx and intense Soret maxima to longer wavelengths. The C3-substitution effect on the redmost absorption and bluemost emission maxima in the N22-methyl-chlorins was smaller than that in the N22-unsubstitutes. In most cases, the N22-methylation increased the Stokes shifts and decreased the fluorescence emission quantum yields and lifetimes, which were ascribable to the flexibility of the distorted N22-methyl-chlorin π-planes." @default.
- W4384938624 created "2023-07-22" @default.
- W4384938624 creator A5028335770 @default.
- W4384938624 creator A5038379688 @default.
- W4384938624 date "2023-11-01" @default.
- W4384938624 modified "2023-10-07" @default.
- W4384938624 title "Synthesis of cationic N-methylated chlorophyll derivatives and C3-substitution effect on their optical properties" @default.
- W4384938624 cites W1483115460 @default.
- W4384938624 cites W1556557726 @default.
- W4384938624 cites W1565268763 @default.
- W4384938624 cites W1963906839 @default.
- W4384938624 cites W1966417880 @default.
- W4384938624 cites W1966923962 @default.
- W4384938624 cites W1973639641 @default.
- W4384938624 cites W1975230502 @default.
- W4384938624 cites W1977129795 @default.
- W4384938624 cites W1977360671 @default.
- W4384938624 cites W1985525021 @default.
- W4384938624 cites W1992885230 @default.
- W4384938624 cites W1998092181 @default.
- W4384938624 cites W2013709214 @default.
- W4384938624 cites W2025835648 @default.
- W4384938624 cites W2027306031 @default.
- W4384938624 cites W2032027404 @default.
- W4384938624 cites W2038309137 @default.
- W4384938624 cites W2041396174 @default.
- W4384938624 cites W2058934384 @default.
- W4384938624 cites W2062211862 @default.
- W4384938624 cites W2069899346 @default.
- W4384938624 cites W2074937744 @default.
- W4384938624 cites W2079169087 @default.
- W4384938624 cites W2083372573 @default.
- W4384938624 cites W2087051370 @default.
- W4384938624 cites W2118950175 @default.
- W4384938624 cites W2122022970 @default.
- W4384938624 cites W2167054688 @default.
- W4384938624 cites W2507824825 @default.
- W4384938624 cites W2508127138 @default.
- W4384938624 cites W2548655428 @default.
- W4384938624 cites W2564223845 @default.
- W4384938624 cites W2772781400 @default.
- W4384938624 cites W3047314975 @default.
- W4384938624 cites W3108343426 @default.
- W4384938624 cites W3124240909 @default.
- W4384938624 cites W4207054378 @default.
- W4384938624 cites W4211163151 @default.
- W4384938624 cites W4220700222 @default.
- W4384938624 cites W4221121739 @default.
- W4384938624 cites W4248426995 @default.
- W4384938624 cites W4280586603 @default.
- W4384938624 cites W4313613104 @default.
- W4384938624 cites W4327971541 @default.
- W4384938624 doi "https://doi.org/10.1016/j.dyepig.2023.111557" @default.
- W4384938624 hasPublicationYear "2023" @default.
- W4384938624 type Work @default.
- W4384938624 citedByCount "0" @default.
- W4384938624 crossrefType "journal-article" @default.
- W4384938624 hasAuthorship W4384938624A5028335770 @default.
- W4384938624 hasAuthorship W4384938624A5038379688 @default.
- W4384938624 hasConcept C120665830 @default.
- W4384938624 hasConcept C121332964 @default.
- W4384938624 hasConcept C125287762 @default.
- W4384938624 hasConcept C159985019 @default.
- W4384938624 hasConcept C171001562 @default.
- W4384938624 hasConcept C178790620 @default.
- W4384938624 hasConcept C183882617 @default.
- W4384938624 hasConcept C185592680 @default.
- W4384938624 hasConcept C192562407 @default.
- W4384938624 hasConcept C2778178086 @default.
- W4384938624 hasConcept C2779480358 @default.
- W4384938624 hasConcept C75473681 @default.
- W4384938624 hasConcept C91881484 @default.
- W4384938624 hasConceptScore W4384938624C120665830 @default.
- W4384938624 hasConceptScore W4384938624C121332964 @default.
- W4384938624 hasConceptScore W4384938624C125287762 @default.
- W4384938624 hasConceptScore W4384938624C159985019 @default.
- W4384938624 hasConceptScore W4384938624C171001562 @default.
- W4384938624 hasConceptScore W4384938624C178790620 @default.
- W4384938624 hasConceptScore W4384938624C183882617 @default.
- W4384938624 hasConceptScore W4384938624C185592680 @default.
- W4384938624 hasConceptScore W4384938624C192562407 @default.
- W4384938624 hasConceptScore W4384938624C2778178086 @default.
- W4384938624 hasConceptScore W4384938624C2779480358 @default.
- W4384938624 hasConceptScore W4384938624C75473681 @default.
- W4384938624 hasConceptScore W4384938624C91881484 @default.
- W4384938624 hasFunder F4320334764 @default.
- W4384938624 hasLocation W43849386241 @default.
- W4384938624 hasOpenAccess W4384938624 @default.
- W4384938624 hasPrimaryLocation W43849386241 @default.
- W4384938624 hasRelatedWork W1969618541 @default.
- W4384938624 hasRelatedWork W1973306937 @default.
- W4384938624 hasRelatedWork W2028878063 @default.
- W4384938624 hasRelatedWork W2031021428 @default.
- W4384938624 hasRelatedWork W2035025222 @default.
- W4384938624 hasRelatedWork W2097737528 @default.
- W4384938624 hasRelatedWork W2132932867 @default.
- W4384938624 hasRelatedWork W2593417436 @default.
- W4384938624 hasRelatedWork W2914256287 @default.