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- W4385007267 abstract "When electrolyte solutions are confined in micro- and nanochannels their conductivity is significantly different from those in a bulk phase. Here we revisit the theory of this phenomenon by focusing attention on the reduction in the ion mobility with the concentration of salt and a consequent impact to the conductivity of a solution, from bulk to confined in a narrow slit. Equations for the zeta potentials and mobilities of ions are derived and used to obtain the expression for a bulk conductivity valid in a much larger concentration range than it was in earlier theories. By extending the formalism to the electrolyte solution in the charged channel the equations describing the conductivity in different modes are presented. They can be regarded as a generalization of prior work on the channel conductivity to a more realistic case of a nonzero reduction of the zeta potential and electrophoretic mobility of ions with salt concentration. Our analysis provides a framework for interpreting measurements on the conductivity of electrolyte solutions in the bulk and in narrow channels" @default.
- W4385007267 created "2023-07-22" @default.
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- W4385007267 date "2023-07-20" @default.
- W4385007267 modified "2023-10-17" @default.
- W4385007267 title "Electrophoresis of ions and elecrolyte conductivity: from bulk to nanochannels" @default.
- W4385007267 doi "https://doi.org/10.48550/arxiv.2307.10921" @default.
- W4385007267 hasPublicationYear "2023" @default.
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