FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4385062189> ?p ?o ?g. }

• W4385062189 endingPage "6045" @default.
• W4385062189 startingPage "6032" @default.
• W4385062189 abstract "Recent studies have utilized AC fields and electrochemical reactions in multicomponent electrolyte solutions to control colloidal assembly. However, theoretical investigations have thus far been limited to binary electrolytes and have overlooked the impact of electrochemical reactions. In this study, we address these limitations by analyzing a system with multicomponent electrolytes, while also relaxing the assumption of ideally blocking electrodes to capture the effect of surface electrochemical reactions. Through a regular perturbation analysis in the low-applied-potential regime, we solve the Poisson-Nernst-Planck equations and obtain effective equations for electrical potential and ion concentrations. By employing a combination of numerical and analytical calculations, our analysis reveals a significant finding: electrochemical reactions alone can generate asymmetric rectified electric fields (AREFs), i.e., time-averaged, long-range electric fields, even when the diffusivities of the ionic species are equal. This finding expands our understanding beyond the conventional notion that AREFs arise solely from diffusivity contrast. Furthermore, we demonstrate that AREFs induced by electrochemical reactions can be stronger than those resulting from asymmetric diffusivities. Additionally, we report the emergence of asymmetric rectified concentration fields (ARCFs), i.e., time-averaged long-range concentration fields, which supports the electrodiffusiophoresis mechanism of colloidal assembly observed in experiments. We also derive analytical expressions for AREFs and ARCFs, emphasizing the role of imbalances in ionic strength and charge densities, respectively, as the driving forces behind their formation. The results presented in this article advance the field of colloidal assembly and also have implications for improved understanding of electrolyte transport in electrochemical devices." @default.
• W4385062189 created "2023-07-23" @default.
• W4385062189 creator A5017754703 @default.
• W4385062189 creator A5081180707 @default.
• W4385062189 creator A5084814608 @default.
• W4385062189 date "2023-01-01" @default.
• W4385062189 modified "2023-10-16" @default.
• W4385062189 title "Asymmetric rectified electric and concentration fields in multicomponent electrolytes with surface reactions" @default.
• W4385062189 cites W125124066 @default.
• W4385062189 cites W1775993386 @default.
• W4385062189 cites W1978241675 @default.
• W4385062189 cites W1984881776 @default.
• W4385062189 cites W1994072032 @default.
• W4385062189 cites W1998513022 @default.
• W4385062189 cites W2001962804 @default.
• W4385062189 cites W2003223598 @default.
• W4385062189 cites W2013434706 @default.
• W4385062189 cites W2029748606 @default.
• W4385062189 cites W2029957547 @default.
• W4385062189 cites W2033730719 @default.
• W4385062189 cites W2044812970 @default.
• W4385062189 cites W2047696693 @default.
• W4385062189 cites W2054712614 @default.
• W4385062189 cites W2059326579 @default.
• W4385062189 cites W2059519116 @default.
• W4385062189 cites W2078047441 @default.
• W4385062189 cites W2088465255 @default.
• W4385062189 cites W2098724168 @default.
• W4385062189 cites W2123790526 @default.
• W4385062189 cites W2134291982 @default.
• W4385062189 cites W2146070336 @default.
• W4385062189 cites W2148141436 @default.
• W4385062189 cites W2153210340 @default.
• W4385062189 cites W2170129644 @default.
• W4385062189 cites W2202771803 @default.
• W4385062189 cites W2319458329 @default.
• W4385062189 cites W2330368019 @default.
• W4385062189 cites W2334638109 @default.
• W4385062189 cites W2335648490 @default.
• W4385062189 cites W2375224876 @default.
• W4385062189 cites W2462538800 @default.
• W4385062189 cites W2567041579 @default.
• W4385062189 cites W2727826478 @default.
• W4385062189 cites W2755269103 @default.
• W4385062189 cites W2782188746 @default.
• W4385062189 cites W2808025896 @default.
• W4385062189 cites W2891247344 @default.
• W4385062189 cites W2899469230 @default.
• W4385062189 cites W2936823778 @default.
• W4385062189 cites W2942988709 @default.
• W4385062189 cites W2952465261 @default.
• W4385062189 cites W2964344211 @default.
• W4385062189 cites W2968612183 @default.
• W4385062189 cites W2999794967 @default.
• W4385062189 cites W3023801515 @default.
• W4385062189 cites W3039289617 @default.
• W4385062189 cites W3046546345 @default.
• W4385062189 cites W3127397675 @default.
• W4385062189 cites W3133304993 @default.
• W4385062189 cites W3177053136 @default.
• W4385062189 cites W3186242866 @default.
• W4385062189 cites W3216705540 @default.
• W4385062189 cites W4213203527 @default.
• W4385062189 cites W4220920626 @default.
• W4385062189 cites W4226030130 @default.
• W4385062189 cites W4285411091 @default.
• W4385062189 cites W4296619097 @default.
• W4385062189 cites W4297173603 @default.
• W4385062189 cites W4313528075 @default.
• W4385062189 cites W4317615166 @default.
• W4385062189 doi "https://doi.org/10.1039/d3sm00823a" @default.
• W4385062189 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37523356" @default.
• W4385062189 hasPublicationYear "2023" @default.
• W4385062189 type Work @default.
• W4385062189 citedByCount "1" @default.
• W4385062189 crossrefType "journal-article" @default.
• W4385062189 hasAuthorship W4385062189A5017754703 @default.
• W4385062189 hasAuthorship W4385062189A5081180707 @default.
• W4385062189 hasAuthorship W4385062189A5084814608 @default.
• W4385062189 hasBestOaLocation W43850621892 @default.
• W4385062189 hasConcept C121332964 @default.
• W4385062189 hasConcept C145148216 @default.
• W4385062189 hasConcept C147789679 @default.
• W4385062189 hasConcept C159467904 @default.
• W4385062189 hasConcept C17525397 @default.
• W4385062189 hasConcept C178790620 @default.
• W4385062189 hasConcept C184501600 @default.
• W4385062189 hasConcept C185592680 @default.
• W4385062189 hasConcept C192562407 @default.
• W4385062189 hasConcept C2182769 @default.
• W4385062189 hasConcept C37668627 @default.
• W4385062189 hasConcept C52859227 @default.
• W4385062189 hasConcept C59789625 @default.
• W4385062189 hasConcept C60799052 @default.
• W4385062189 hasConcept C62520636 @default.
• W4385062189 hasConcept C68801617 @default.
• W4385062189 hasConcept C97355855 @default.
• W4385062189 hasConceptScore W4385062189C121332964 @default.

• next