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• W4385075794 abstract "A series of bis-P,O-hybrid ligands (L1-L4) were synthesized and characterized. The crystal structures demonstrated that the ligand of L2, 1,4-bis((2-(diphenylphosphaneyl)phenoxy)methyl)benzene, not only acted as a typical trans-positioned diphosphine as observed in the complexes Pd(L2)(OAc)2 and Pd(L2)Cl2, but also potentially as a P,P,O-tripodal pincer. As a result, under mild conditions (80 ℃, 0.5∼3.0 MPa), L2 enabled Pd(OAc)2 to exhibit remarkable performance in terms of high activity and excellent regioselectivity (l/b > 97/3) in the alkoxycarbonylation of vinyl arenes with the isolated yields of 57∼91%." @default.
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• W4385075794 date "2023-10-01" @default.
• W4385075794 modified "2023-09-27" @default.
• W4385075794 title "Novel bis-P,O-hybrid-ligand modified Pd-catalyst for highly selective anti-Markovnikov alkoxycarbonylation of alkenes under mild conditions" @default.
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• W4385075794 doi "https://doi.org/10.1016/j.jcat.2023.07.007" @default.
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