Matches in SemOpenAlex for { <https://semopenalex.org/work/W4385186296> ?p ?o ?g. }
- W4385186296 abstract "Selective C-O bond cleavage is an efficient way for the biomass valorization to value-added chemicals, but is challenged to be operated at room temperature via conventional thermal catalysis. Herein, inspired from the DNA biosynthesis which involves a radical-mediated spin-center shift (SCS) C-O bond cleavage process, we report a biomimetic room-temperature C-O bond cleavage of vicinal diol (HOCHCH-OH). We construct a Mn doped CdS (Mn/CdS) as a photocatalyst to mimic the biologic SCS process. The Mn site plays pivotal role: (1) accelerates the photo-induced carrier separation, promoting the hole-mediated C-H bond cleavage to generate carbon-centered radicals, and (2) serves as the binding site for -OH groups, making it to be an easier leaving group. Mn/CdS achieves 0.28 mmol gcat-1 h-1 of hydroxyacetone (HA) from glycerol dehydration at room temperature under visible light irradiation, which is 3.5-fold that over pristine CdS and 40-fold that over bulk MnS/CdS. This study provides a new biomimetic room-temperature C-O bond cleavage process, which is promising for the biomass valorization." @default.
- W4385186296 created "2023-07-25" @default.
- W4385186296 creator A5038241246 @default.
- W4385186296 creator A5056500996 @default.
- W4385186296 creator A5073681920 @default.
- W4385186296 date "2023-08-10" @default.
- W4385186296 modified "2023-10-09" @default.
- W4385186296 title "Photoinduced biomimetic room‐temperature C−O bond cleavage over Mn doped CdS" @default.
- W4385186296 cites W1750457094 @default.
- W4385186296 cites W1979544533 @default.
- W4385186296 cites W1981368803 @default.
- W4385186296 cites W1982267818 @default.
- W4385186296 cites W1985718302 @default.
- W4385186296 cites W1994147732 @default.
- W4385186296 cites W1999057729 @default.
- W4385186296 cites W2006491564 @default.
- W4385186296 cites W2007395042 @default.
- W4385186296 cites W2023022618 @default.
- W4385186296 cites W2028919804 @default.
- W4385186296 cites W2030206647 @default.
- W4385186296 cites W2032839609 @default.
- W4385186296 cites W2036113194 @default.
- W4385186296 cites W2042804012 @default.
- W4385186296 cites W2043350421 @default.
- W4385186296 cites W2051335599 @default.
- W4385186296 cites W2051426830 @default.
- W4385186296 cites W2054835073 @default.
- W4385186296 cites W2056768042 @default.
- W4385186296 cites W2059477963 @default.
- W4385186296 cites W2066092969 @default.
- W4385186296 cites W2069579320 @default.
- W4385186296 cites W2085972813 @default.
- W4385186296 cites W2114075309 @default.
- W4385186296 cites W2115293107 @default.
- W4385186296 cites W2118030354 @default.
- W4385186296 cites W2120446525 @default.
- W4385186296 cites W2133363052 @default.
- W4385186296 cites W2297399199 @default.
- W4385186296 cites W2322842605 @default.
- W4385186296 cites W2340492682 @default.
- W4385186296 cites W2422488648 @default.
- W4385186296 cites W2581051268 @default.
- W4385186296 cites W2583749587 @default.
- W4385186296 cites W2586489205 @default.
- W4385186296 cites W2605521920 @default.
- W4385186296 cites W2771068954 @default.
- W4385186296 cites W2782131232 @default.
- W4385186296 cites W2786747722 @default.
- W4385186296 cites W2789643047 @default.
- W4385186296 cites W2790765438 @default.
- W4385186296 cites W2791859160 @default.
- W4385186296 cites W2890597636 @default.
- W4385186296 cites W2913700886 @default.
- W4385186296 cites W2939759892 @default.
- W4385186296 cites W2948096633 @default.
- W4385186296 cites W2960426398 @default.
- W4385186296 cites W3006328145 @default.
- W4385186296 cites W3041490169 @default.
- W4385186296 cites W3047078929 @default.
- W4385186296 cites W3083605458 @default.
- W4385186296 cites W3087117600 @default.
- W4385186296 cites W3088285102 @default.
- W4385186296 cites W3091336126 @default.
- W4385186296 cites W3091979054 @default.
- W4385186296 cites W3093582156 @default.
- W4385186296 cites W3095335987 @default.
- W4385186296 cites W3116350772 @default.
- W4385186296 cites W3153401658 @default.
- W4385186296 cites W3158653098 @default.
- W4385186296 cites W3158926249 @default.
- W4385186296 cites W3204645196 @default.
- W4385186296 cites W4211218458 @default.
- W4385186296 cites W4240180778 @default.
- W4385186296 cites W788427216 @default.
- W4385186296 doi "https://doi.org/10.1002/cssc.202300727" @default.
- W4385186296 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37486587" @default.
- W4385186296 hasPublicationYear "2023" @default.
- W4385186296 type Work @default.
- W4385186296 citedByCount "0" @default.
- W4385186296 crossrefType "journal-article" @default.
- W4385186296 hasAuthorship W4385186296A5038241246 @default.
- W4385186296 hasAuthorship W4385186296A5056500996 @default.
- W4385186296 hasAuthorship W4385186296A5073681920 @default.
- W4385186296 hasConcept C121349320 @default.
- W4385186296 hasConcept C139066938 @default.
- W4385186296 hasConcept C159985019 @default.
- W4385186296 hasConcept C161790260 @default.
- W4385186296 hasConcept C175156509 @default.
- W4385186296 hasConcept C178790620 @default.
- W4385186296 hasConcept C185592680 @default.
- W4385186296 hasConcept C192562407 @default.
- W4385186296 hasConcept C3044715 @default.
- W4385186296 hasConcept C43369102 @default.
- W4385186296 hasConcept C65165184 @default.
- W4385186296 hasConcept C75473681 @default.
- W4385186296 hasConceptScore W4385186296C121349320 @default.
- W4385186296 hasConceptScore W4385186296C139066938 @default.
- W4385186296 hasConceptScore W4385186296C159985019 @default.
- W4385186296 hasConceptScore W4385186296C161790260 @default.
- W4385186296 hasConceptScore W4385186296C175156509 @default.