Matches in SemOpenAlex for { <https://semopenalex.org/work/W4385189867> ?p ?o ?g. }
- W4385189867 abstract "High entropy alloys (HEAs) are highly suitable candidate catalysts for oxygen evolution and reduction reactions (OER/ORR) as they offer numerous parameters for optimizing the electronic structure and catalytic sites. Herein, FeCoNiMoW HEA nanoparticles are synthesized using a solution-based low-temperature approach. Such FeCoNiMoW nanoparticles show high entropy properties, subtle lattice distortions, and modulated electronic structure, leading to superior OER performance with an overpotential of 233 mV at 10 mA cm-2 and 276 mV at 100 mA cm-2 . Density functional theory calculations reveal the electronic structures of the FeCoNiMoW active sites with an optimized d-band center position that enables suitable adsorption of OOH* intermediates and reduces the Gibbs free energy barrier in the OER process. Aqueous zinc-air batteries (ZABs) based on this HEA demonstrate a high open circuit potential of 1.59 V, a peak power density of 116.9 mW cm-2 , a specific capacity of 857 mAh gZn-1, and excellent stability for over 660 h of continuous charge-discharge cycles. Flexible and solid ZABs are also assembled and tested, displaying excellent charge-discharge performance at different bending angles. This work shows the significance of 4d/5d metal-modulated electronic structure and optimized adsorption ability to improve the performance of OER/ORR, ZABs, and beyond." @default.
- W4385189867 created "2023-07-25" @default.
- W4385189867 creator A5021076766 @default.
- W4385189867 creator A5030023423 @default.
- W4385189867 creator A5036560264 @default.
- W4385189867 creator A5039201206 @default.
- W4385189867 creator A5043063276 @default.
- W4385189867 creator A5043078609 @default.
- W4385189867 creator A5055144058 @default.
- W4385189867 creator A5055487387 @default.
- W4385189867 creator A5057352688 @default.
- W4385189867 creator A5059565749 @default.
- W4385189867 creator A5071773009 @default.
- W4385189867 creator A5080731706 @default.
- W4385189867 creator A5083955309 @default.
- W4385189867 creator A5090250478 @default.
- W4385189867 date "2023-10-15" @default.
- W4385189867 modified "2023-10-18" @default.
- W4385189867 title "A 3d‐4d‐5d High Entropy Alloy as a Bifunctional Oxygen Catalyst for Robust Aqueous Zinc‐Air Batteries" @default.
- W4385189867 cites W1864897624 @default.
- W4385189867 cites W1965783559 @default.
- W4385189867 cites W2055125499 @default.
- W4385189867 cites W2056550602 @default.
- W4385189867 cites W2103522698 @default.
- W4385189867 cites W2163323348 @default.
- W4385189867 cites W2331165403 @default.
- W4385189867 cites W2335046664 @default.
- W4385189867 cites W2558095361 @default.
- W4385189867 cites W2614522063 @default.
- W4385189867 cites W2803282983 @default.
- W4385189867 cites W2895997958 @default.
- W4385189867 cites W2900840313 @default.
- W4385189867 cites W2903672689 @default.
- W4385189867 cites W2945316184 @default.
- W4385189867 cites W2946117300 @default.
- W4385189867 cites W2951644190 @default.
- W4385189867 cites W2974417623 @default.
- W4385189867 cites W2978488956 @default.
- W4385189867 cites W2979750733 @default.
- W4385189867 cites W2981701251 @default.
- W4385189867 cites W2982955030 @default.
- W4385189867 cites W2999372363 @default.
- W4385189867 cites W3008757921 @default.
- W4385189867 cites W3046126518 @default.
- W4385189867 cites W3091529119 @default.
- W4385189867 cites W3092720035 @default.
- W4385189867 cites W310769362 @default.
- W4385189867 cites W3109897543 @default.
- W4385189867 cites W3139126413 @default.
- W4385189867 cites W3140549205 @default.
- W4385189867 cites W3152579142 @default.
- W4385189867 cites W3164962759 @default.
- W4385189867 cites W3166417520 @default.
- W4385189867 cites W3196321700 @default.
- W4385189867 cites W3205212392 @default.
- W4385189867 cites W3208105901 @default.
- W4385189867 cites W4200183657 @default.
- W4385189867 cites W4200590576 @default.
- W4385189867 cites W4210317245 @default.
- W4385189867 cites W4220915691 @default.
- W4385189867 cites W4226166932 @default.
- W4385189867 cites W4282842760 @default.
- W4385189867 cites W4283524579 @default.
- W4385189867 cites W4286252891 @default.
- W4385189867 cites W4292296496 @default.
- W4385189867 cites W4292937911 @default.
- W4385189867 cites W4294958851 @default.
- W4385189867 cites W4295008849 @default.
- W4385189867 cites W4295919669 @default.
- W4385189867 cites W4297222237 @default.
- W4385189867 cites W4306631581 @default.
- W4385189867 cites W4308490481 @default.
- W4385189867 cites W4312113502 @default.
- W4385189867 cites W4313251574 @default.
- W4385189867 cites W4313490828 @default.
- W4385189867 cites W4313812423 @default.
- W4385189867 cites W4317780655 @default.
- W4385189867 cites W4318473555 @default.
- W4385189867 cites W4318579211 @default.
- W4385189867 cites W4328135912 @default.
- W4385189867 cites W4379014174 @default.
- W4385189867 cites W827703054 @default.
- W4385189867 doi "https://doi.org/10.1002/adma.202303719" @default.
- W4385189867 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37487245" @default.
- W4385189867 hasPublicationYear "2023" @default.
- W4385189867 type Work @default.
- W4385189867 citedByCount "1" @default.
- W4385189867 countsByYear W43851898672023 @default.
- W4385189867 crossrefType "journal-article" @default.
- W4385189867 hasAuthorship W4385189867A5021076766 @default.
- W4385189867 hasAuthorship W4385189867A5030023423 @default.
- W4385189867 hasAuthorship W4385189867A5036560264 @default.
- W4385189867 hasAuthorship W4385189867A5039201206 @default.
- W4385189867 hasAuthorship W4385189867A5043063276 @default.
- W4385189867 hasAuthorship W4385189867A5043078609 @default.
- W4385189867 hasAuthorship W4385189867A5055144058 @default.
- W4385189867 hasAuthorship W4385189867A5055487387 @default.
- W4385189867 hasAuthorship W4385189867A5057352688 @default.
- W4385189867 hasAuthorship W4385189867A5059565749 @default.
- W4385189867 hasAuthorship W4385189867A5071773009 @default.