FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4385192013> ?p ?o ?g. }

• W4385192013 endingPage "123193" @default.
• W4385192013 startingPage "123193" @default.
• W4385192013 abstract "Molecular systems with intense exciplex luminescence are promising for the creation of OLEDs and light-transforming materials. The luminescent properties of difluoroboron meta- and para-nitrodibenzoylmethanates (1 and 2) were studied by the steady-state and time-resolved luminescence spectroscopy methods and quantum chemistry simulation. The influence of the position of the nitro group on the spectral properties of the complexes was revealed. The nitro group withdraws the electron density upon photoexcitation in the para-isomer in contrast to the meta-isomer. The bond order of the C–C bond between the phenyl and chelate rings decreases in the excited relaxed state of 2, which leads to rotation of the substituent and a low quantum yield. Formation of exciplexes of 1 and 2 in benzene, toluene and polystyrene was found. The formation of the ground and excited-state electron donor-acceptor complexes based on difluoroboron nitrodibenzoylmethanates and benzene was revealed. The TD DFT method showed that the complexes are characterized by the presence of short contacts between the fluorine atom of the dye molecule and the hydrogen atoms of the aromatic hydrocarbon molecule. These contacts shorten during the transition from the ground state to the excited state. Polymeric compositions based on PS and PMMA doped with 1 and 2 were obtained. The luminescence intensity of dyes 1 and 2 increases during the transition from PMMA to PS. A significant bathochromic shift of the luminescence maximum of 1 is observed, which is associated with the formation of exciplexes and triplexes. The obtained polymeric materials are promising for the development of optical smart materials." @default.
• W4385192013 created "2023-07-25" @default.
• W4385192013 creator A5012601048 @default.
• W4385192013 creator A5013365869 @default.
• W4385192013 creator A5033514942 @default.
• W4385192013 creator A5053595941 @default.
• W4385192013 creator A5086871547 @default.
• W4385192013 date "2023-12-01" @default.
• W4385192013 modified "2023-09-26" @default.
• W4385192013 title "Exciplex Luminescence of Difluoroboron meta- and para-Nitrodibenzoylmethanates in Solutions and Polymer Matrix" @default.
• W4385192013 cites W1489590484 @default.
• W4385192013 cites W1960196470 @default.
• W4385192013 cites W1963818842 @default.
• W4385192013 cites W1964395868 @default.
• W4385192013 cites W1965340878 @default.
• W4385192013 cites W1971578813 @default.
• W4385192013 cites W1976271587 @default.
• W4385192013 cites W1983048065 @default.
• W4385192013 cites W1996311157 @default.
• W4385192013 cites W1996428793 @default.
• W4385192013 cites W1997729983 @default.
• W4385192013 cites W1998331235 @default.
• W4385192013 cites W2005259257 @default.
• W4385192013 cites W2008420355 @default.
• W4385192013 cites W2017003093 @default.
• W4385192013 cites W2022950330 @default.
• W4385192013 cites W2025070636 @default.
• W4385192013 cites W2032185182 @default.
• W4385192013 cites W2033729256 @default.
• W4385192013 cites W2037724803 @default.
• W4385192013 cites W2042631320 @default.
• W4385192013 cites W2054462058 @default.
• W4385192013 cites W2055449504 @default.
• W4385192013 cites W2059029765 @default.
• W4385192013 cites W2061957367 @default.
• W4385192013 cites W2066074990 @default.
• W4385192013 cites W2080318794 @default.
• W4385192013 cites W2087281054 @default.
• W4385192013 cites W2101367315 @default.
• W4385192013 cites W2107154407 @default.
• W4385192013 cites W2110933289 @default.
• W4385192013 cites W2128059844 @default.
• W4385192013 cites W2143981217 @default.
• W4385192013 cites W2144391591 @default.
• W4385192013 cites W2157224535 @default.
• W4385192013 cites W2158274572 @default.
• W4385192013 cites W2159182565 @default.
• W4385192013 cites W2169888415 @default.
• W4385192013 cites W2269445948 @default.
• W4385192013 cites W2328987331 @default.
• W4385192013 cites W2331083814 @default.
• W4385192013 cites W2460897971 @default.
• W4385192013 cites W2768964848 @default.
• W4385192013 cites W2771700172 @default.
• W4385192013 cites W2884774054 @default.
• W4385192013 cites W2900495886 @default.
• W4385192013 cites W2978076197 @default.
• W4385192013 cites W3020680835 @default.
• W4385192013 cites W3026502451 @default.
• W4385192013 cites W3092192239 @default.
• W4385192013 cites W3135694171 @default.
• W4385192013 cites W3155886799 @default.
• W4385192013 cites W3201133876 @default.
• W4385192013 cites W3208358920 @default.
• W4385192013 cites W4284966725 @default.
• W4385192013 cites W4295852635 @default.
• W4385192013 cites W2002832830 @default.
• W4385192013 doi "https://doi.org/10.1016/j.saa.2023.123193" @default.
• W4385192013 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37515888" @default.
• W4385192013 hasPublicationYear "2023" @default.
• W4385192013 type Work @default.
• W4385192013 citedByCount "0" @default.
• W4385192013 crossrefType "journal-article" @default.
• W4385192013 hasAuthorship W4385192013A5012601048 @default.
• W4385192013 hasAuthorship W4385192013A5013365869 @default.
• W4385192013 hasAuthorship W4385192013A5033514942 @default.
• W4385192013 hasAuthorship W4385192013A5053595941 @default.
• W4385192013 hasAuthorship W4385192013A5086871547 @default.
• W4385192013 hasConcept C121332964 @default.
• W4385192013 hasConcept C148869448 @default.
• W4385192013 hasConcept C155220765 @default.
• W4385192013 hasConcept C171001562 @default.
• W4385192013 hasConcept C178790620 @default.
• W4385192013 hasConcept C181500209 @default.
• W4385192013 hasConcept C184779094 @default.
• W4385192013 hasConcept C185592680 @default.
• W4385192013 hasConcept C192562407 @default.
• W4385192013 hasConcept C32909587 @default.
• W4385192013 hasConcept C46051903 @default.
• W4385192013 hasConcept C49040817 @default.
• W4385192013 hasConcept C62520636 @default.
• W4385192013 hasConcept C69523127 @default.
• W4385192013 hasConcept C75473681 @default.
• W4385192013 hasConcept C91881484 @default.
• W4385192013 hasConceptScore W4385192013C121332964 @default.
• W4385192013 hasConceptScore W4385192013C148869448 @default.
• W4385192013 hasConceptScore W4385192013C155220765 @default.
• W4385192013 hasConceptScore W4385192013C171001562 @default.

• next