FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4385216013> ?p ?o ?g. }

• W4385216013 endingPage "6002" @default.
• W4385216013 startingPage "5993" @default.
• W4385216013 abstract "We have determined the crystal structures of highly regioregular (>97% HT additions) isotactic- and atactic-poly(1-pentamethylene alcohol)s (PPMA, −[(CH2)4CH(OH)]n−) by a quantitative analysis of 2-dimensional wide-angle X-ray diffraction data. The unit cell houses two chains in a planar-zigzag conformation, with orthorhombic symmetry and parameters a = 8.637 Å, b = 4.987 Å and c (chain axis) = 12.840 Å for the it-PPMA and a = 8.76 Å, b = 5.06 Å, and c (chain axis) = 12.840 Å for the at-PPMA. The space group is P212121 for both polymers. The zigzag planes are nearly parallel to the rolled plane of the doubly oriented sample. These regularly packed chains are aggregated in twinned domains having two opposite orientations of the unit cells. In the case of at-PPMA, the random stereochemical positioning of the alcohol pendants results in a more expanded unit cell than the corresponding cell of it-PPMA. Intermolecular hydrogen bonds form along the b axis for both the it- and at-species, the strength of which is slightly different depending on the OH configuration, as judged from infrared spectral information as well as the O···O intermolecular distances." @default.
• W4385216013 created "2023-07-25" @default.
• W4385216013 creator A5003081984 @default.
• W4385216013 creator A5010969658 @default.
• W4385216013 creator A5053607457 @default.
• W4385216013 creator A5064737851 @default.
• W4385216013 creator A5069309772 @default.
• W4385216013 date "2023-07-24" @default.
• W4385216013 modified "2023-10-16" @default.
• W4385216013 title "Crystal Structures of Isotactic and Atactic Poly(1-pentamethylene alcohol)" @default.
• W4385216013 cites W1971051856 @default.
• W4385216013 cites W1974702475 @default.
• W4385216013 cites W1994726088 @default.
• W4385216013 cites W1997689272 @default.
• W4385216013 cites W2007746219 @default.
• W4385216013 cites W2014518997 @default.
• W4385216013 cites W2015006908 @default.
• W4385216013 cites W2015062403 @default.
• W4385216013 cites W2016157712 @default.
• W4385216013 cites W2034031296 @default.
• W4385216013 cites W2035078416 @default.
• W4385216013 cites W2040526004 @default.
• W4385216013 cites W2041520002 @default.
• W4385216013 cites W2063429697 @default.
• W4385216013 cites W2068394853 @default.
• W4385216013 cites W2072852786 @default.
• W4385216013 cites W2076406407 @default.
• W4385216013 cites W2081970247 @default.
• W4385216013 cites W2091654157 @default.
• W4385216013 cites W2100878678 @default.
• W4385216013 cites W2169108026 @default.
• W4385216013 cites W2319511825 @default.
• W4385216013 cites W25156926 @default.
• W4385216013 cites W2766757002 @default.
• W4385216013 cites W3042426191 @default.
• W4385216013 cites W4246699049 @default.
• W4385216013 cites W4285273038 @default.
• W4385216013 cites W4286587775 @default.
• W4385216013 cites W4322626119 @default.
• W4385216013 doi "https://doi.org/10.1021/acs.macromol.3c01060" @default.
• W4385216013 hasPublicationYear "2023" @default.
• W4385216013 type Work @default.
• W4385216013 citedByCount "0" @default.
• W4385216013 crossrefType "journal-article" @default.
• W4385216013 hasAuthorship W4385216013A5003081984 @default.
• W4385216013 hasAuthorship W4385216013A5010969658 @default.
• W4385216013 hasAuthorship W4385216013A5053607457 @default.
• W4385216013 hasAuthorship W4385216013A5064737851 @default.
• W4385216013 hasAuthorship W4385216013A5069309772 @default.
• W4385216013 hasConcept C112887158 @default.
• W4385216013 hasConcept C115624301 @default.
• W4385216013 hasConcept C159985019 @default.
• W4385216013 hasConcept C166950319 @default.
• W4385216013 hasConcept C178790620 @default.
• W4385216013 hasConcept C185592680 @default.
• W4385216013 hasConcept C192271897 @default.
• W4385216013 hasConcept C192562407 @default.
• W4385216013 hasConcept C199360897 @default.
• W4385216013 hasConcept C2524010 @default.
• W4385216013 hasConcept C2781285689 @default.
• W4385216013 hasConcept C32909587 @default.
• W4385216013 hasConcept C33923547 @default.
• W4385216013 hasConcept C37243968 @default.
• W4385216013 hasConcept C41008148 @default.
• W4385216013 hasConcept C44228677 @default.
• W4385216013 hasConcept C521977710 @default.
• W4385216013 hasConcept C58018886 @default.
• W4385216013 hasConcept C8010536 @default.
• W4385216013 hasConceptScore W4385216013C112887158 @default.
• W4385216013 hasConceptScore W4385216013C115624301 @default.
• W4385216013 hasConceptScore W4385216013C159985019 @default.
• W4385216013 hasConceptScore W4385216013C166950319 @default.
• W4385216013 hasConceptScore W4385216013C178790620 @default.
• W4385216013 hasConceptScore W4385216013C185592680 @default.
• W4385216013 hasConceptScore W4385216013C192271897 @default.
• W4385216013 hasConceptScore W4385216013C192562407 @default.
• W4385216013 hasConceptScore W4385216013C199360897 @default.
• W4385216013 hasConceptScore W4385216013C2524010 @default.
• W4385216013 hasConceptScore W4385216013C2781285689 @default.
• W4385216013 hasConceptScore W4385216013C32909587 @default.
• W4385216013 hasConceptScore W4385216013C33923547 @default.
• W4385216013 hasConceptScore W4385216013C37243968 @default.
• W4385216013 hasConceptScore W4385216013C41008148 @default.
• W4385216013 hasConceptScore W4385216013C44228677 @default.
• W4385216013 hasConceptScore W4385216013C521977710 @default.
• W4385216013 hasConceptScore W4385216013C58018886 @default.
• W4385216013 hasConceptScore W4385216013C8010536 @default.
• W4385216013 hasFunder F4320337367 @default.
• W4385216013 hasIssue "15" @default.
• W4385216013 hasLocation W43852160131 @default.
• W4385216013 hasOpenAccess W4385216013 @default.
• W4385216013 hasPrimaryLocation W43852160131 @default.
• W4385216013 hasRelatedWork W1969036027 @default.
• W4385216013 hasRelatedWork W1989004737 @default.
• W4385216013 hasRelatedWork W2013207129 @default.
• W4385216013 hasRelatedWork W2028104741 @default.
• W4385216013 hasRelatedWork W2072417293 @default.
• W4385216013 hasRelatedWork W2109919885 @default.

• next