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• W4385231180 abstract "Reaction of sulfonimidoyl fluorides with anilines and Ca(NTf2)2 results in the formation of chiral sulfonimidamides. The reaction proceeds with inversion of the stereocenter at a sulfur atom. Enantiospecificity of the reaction was observed for all studied non-heterocyclic anilines. Combined experimental and computational mechanistic studies highlight chelate-type coordination of the sulfonimidoyl group to Ca(NTf2)2 and the formation of a SN2-like transition state, in which leaving F- coordinates with the Ca2+ ion." @default.
• W4385231180 created "2023-07-26" @default.
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• W4385231180 date "2023-07-25" @default.
• W4385231180 modified "2023-10-09" @default.
• W4385231180 title "Enantiospecific Synthesis of Aniline-Derived Sulfonimidamides" @default.
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• W4385231180 doi "https://doi.org/10.1021/acs.orglett.3c02132" @default.
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