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- W4385334577 abstract "Abstract Mechanical bonds have been utilized as promising motifs to construct mechanically interlocked aerogels (MIAs) with mechanical adaptivity and multifunctionality. However, fabricating such aerogels with not only precise chemical structures but also dynamic features remains challenging. Herein, we present MIAs carrying dense [2]rotaxane units, which bestow both the stability and flexibility of the aerogel network. Owing to the stable chemical structure of a [2]rotaxane, MIAs possessing a precise and full‐scale mechanically interlocked network could be fabricated with the aid of diverse solvents. In addition, the dynamic nature of the [2]rotaxane resulted in morphologies and mechanical performances of the MIAs that can be dramatically modulated under chemical stimuli. We hope that the structure–property relationship in MIAs will facilitate the development of mechanically interlocked materials and provide novel opportunities toward constructing smart materials with multifunctionalities." @default.
- W4385334577 created "2023-07-29" @default.
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- W4385334577 date "2023-08-07" @default.
- W4385334577 modified "2023-09-24" @default.
- W4385334577 title "Mechanically Interlocked [2]Rotaxane Aerogels with Tunable Morphologies and Mechanical Properties" @default.
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- W4385334577 doi "https://doi.org/10.1002/ange.202306489" @default.
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