Matches in SemOpenAlex for { <https://semopenalex.org/work/W4385368642> ?p ?o ?g. }
- W4385368642 endingPage "119351" @default.
- W4385368642 startingPage "119351" @default.
- W4385368642 abstract "The selective oxidation of phenol into cis, cis-muconic acid was carried out with α-zirconium phosphate supported-copper catalysts. It has been found that a sole α-zirconium phosphate exhibited a preferential selectivity (up to 80%) towards dihydroxybenzene (Catechol/Hydroquinone=1.4:1). Moreover, the further studies indicated that α-zirconium phosphate-supported copper catalysts enable to catalyze the oxidative cleavage of catechol into high-added valuable platform molecule cis,cis-muconic acid (ccMA) by in-situ generating performic acid. A 66% conversion of phenol and 60% selectivity towards cis, cis-muconic acid were obtained under mild reaction condition (30 °C, 2 h). The detailed characterization by means of XRD, SEM, TEM, and pyridine-absorbed FT-IR techniques demonstrated that copper(II) species were highly dispersed on α-zirconium phosphate, and could be bonded with the phosphate group of the support. The forming Cu(II)-O-P linkage was proved to be catalytically active species and endowed the supported-copper catalysts with a superior recyclability. The reaction pathway involved hydroxylation of phenol to give a mixture of catechol (CL) and hydroquinone (HQ), followed by the formation of a metal-catechol complex which was then rapidly oxidized into cis, cis-muconic acid (ccMA)." @default.
- W4385368642 created "2023-07-29" @default.
- W4385368642 creator A5023180240 @default.
- W4385368642 creator A5031493683 @default.
- W4385368642 creator A5045350805 @default.
- W4385368642 creator A5052034716 @default.
- W4385368642 creator A5055700427 @default.
- W4385368642 creator A5065518283 @default.
- W4385368642 creator A5083899414 @default.
- W4385368642 creator A5085963164 @default.
- W4385368642 date "2023-08-01" @default.
- W4385368642 modified "2023-10-12" @default.
- W4385368642 title "Zirconium phosphate supported copper catalyst for selective oxidation of phenol to cis, cis-muconic acid" @default.
- W4385368642 cites W1781361327 @default.
- W4385368642 cites W1965741891 @default.
- W4385368642 cites W1968018387 @default.
- W4385368642 cites W1971931018 @default.
- W4385368642 cites W1980940992 @default.
- W4385368642 cites W1985610280 @default.
- W4385368642 cites W1990986101 @default.
- W4385368642 cites W1994325932 @default.
- W4385368642 cites W1994996040 @default.
- W4385368642 cites W2001651535 @default.
- W4385368642 cites W2013897997 @default.
- W4385368642 cites W2014920636 @default.
- W4385368642 cites W2019824811 @default.
- W4385368642 cites W2021661694 @default.
- W4385368642 cites W2022515197 @default.
- W4385368642 cites W2025430814 @default.
- W4385368642 cites W2026695731 @default.
- W4385368642 cites W2028256950 @default.
- W4385368642 cites W2032571157 @default.
- W4385368642 cites W2035210722 @default.
- W4385368642 cites W2035837247 @default.
- W4385368642 cites W2044005623 @default.
- W4385368642 cites W2046016018 @default.
- W4385368642 cites W2048593286 @default.
- W4385368642 cites W2053904971 @default.
- W4385368642 cites W2060040584 @default.
- W4385368642 cites W2060158239 @default.
- W4385368642 cites W2060242609 @default.
- W4385368642 cites W2073551058 @default.
- W4385368642 cites W2079998464 @default.
- W4385368642 cites W2091069926 @default.
- W4385368642 cites W2097321270 @default.
- W4385368642 cites W2107480049 @default.
- W4385368642 cites W2124440245 @default.
- W4385368642 cites W2290796678 @default.
- W4385368642 cites W23434498 @default.
- W4385368642 cites W2591440800 @default.
- W4385368642 cites W2745194966 @default.
- W4385368642 cites W2767710929 @default.
- W4385368642 cites W2806576602 @default.
- W4385368642 cites W2911564421 @default.
- W4385368642 cites W2913784457 @default.
- W4385368642 cites W2948437718 @default.
- W4385368642 cites W2949457056 @default.
- W4385368642 cites W2952128572 @default.
- W4385368642 cites W3004551120 @default.
- W4385368642 cites W3035368317 @default.
- W4385368642 cites W3040724554 @default.
- W4385368642 cites W3046934226 @default.
- W4385368642 cites W3056317728 @default.
- W4385368642 cites W3082400378 @default.
- W4385368642 cites W3094960639 @default.
- W4385368642 cites W3160774577 @default.
- W4385368642 cites W3182762455 @default.
- W4385368642 cites W4210772426 @default.
- W4385368642 cites W4250873254 @default.
- W4385368642 cites W4318757052 @default.
- W4385368642 doi "https://doi.org/10.1016/j.apcata.2023.119351" @default.
- W4385368642 hasPublicationYear "2023" @default.
- W4385368642 type Work @default.
- W4385368642 citedByCount "0" @default.
- W4385368642 crossrefType "journal-article" @default.
- W4385368642 hasAuthorship W4385368642A5023180240 @default.
- W4385368642 hasAuthorship W4385368642A5031493683 @default.
- W4385368642 hasAuthorship W4385368642A5045350805 @default.
- W4385368642 hasAuthorship W4385368642A5052034716 @default.
- W4385368642 hasAuthorship W4385368642A5055700427 @default.
- W4385368642 hasAuthorship W4385368642A5065518283 @default.
- W4385368642 hasAuthorship W4385368642A5083899414 @default.
- W4385368642 hasAuthorship W4385368642A5085963164 @default.
- W4385368642 hasConcept C118792377 @default.
- W4385368642 hasConcept C13965031 @default.
- W4385368642 hasConcept C161790260 @default.
- W4385368642 hasConcept C178790620 @default.
- W4385368642 hasConcept C179104552 @default.
- W4385368642 hasConcept C185592680 @default.
- W4385368642 hasConcept C2776234857 @default.
- W4385368642 hasConcept C2777550763 @default.
- W4385368642 hasConcept C2777691172 @default.
- W4385368642 hasConcept C2777702071 @default.
- W4385368642 hasConcept C2777713698 @default.
- W4385368642 hasConcept C534791751 @default.
- W4385368642 hasConcept C544778455 @default.
- W4385368642 hasConceptScore W4385368642C118792377 @default.
- W4385368642 hasConceptScore W4385368642C13965031 @default.