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- W4385376018 abstract "Environmental concerns raise the urgent demand of recyclable materials for electrical and electronic applications. Epoxy and its glass fiber reinforced composites are the most widely used materials in these areas, but are generally unrecyclable. Herein, we reported a recyclable epoxy vitrimer and its glass fiber reinforced composite by using salen agent and DGEBA-type epoxy to ensure its molecular design flexibility and industrial adaptability. Comparing with the conventional amine-cured epoxy, the obtained epoxy vitrimer shows a higher glass transition temperature of 140 °C, a superior tensile strength of 86.7 MPa and an enhanced breakdown strength (180 MV m−1). Furthermore, based on the reversible imine-imine and amine−imine exchange reactions, the epoxy vitrimer could be recycled by both mechanical and chemical methods. An admirable recycling efficiency was achieved based on electrical properties. Moreover, its corresponding glass fiber reinforced composites could be recycled in a closed-loop way while the reclaimed fabric was comparable to its origin. This study demonstrates the potential application of salen agent to develop fully recyclable electrical insulating component and opens a window to further improve the material properties of epoxy vitrimer based on the great design flexibility of salen agent." @default.
- W4385376018 created "2023-07-30" @default.
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- W4385376018 date "2023-09-01" @default.
- W4385376018 modified "2023-09-27" @default.
- W4385376018 title "Thermo-mechanical and insulating robust epoxy vitrimer for fully recyclable fiber reinforced composites relied on salen agent" @default.
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- W4385376018 doi "https://doi.org/10.1016/j.polymer.2023.126233" @default.
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