Matches in SemOpenAlex for { <https://semopenalex.org/work/W4385392014> ?p ?o ?g. }
- W4385392014 endingPage "129312" @default.
- W4385392014 startingPage "129312" @default.
- W4385392014 abstract "Biomass-derived furfural and its derivatives are promising feedstocks for producing valuable C5 diols by catalytic hydrolysis. However, this process requires selective ring opening of tetrahydrofurfuryl alcohol (THFA) to 1,5-pentanediol, which is challenging. Here we report efficient route for this conversion using Ni-La(OH)3 catalysts prepared by a green co-precipitation-hydrothermal method. We show that these catalysts can achieve up to 91.7% yield and 94.6% selectivity of 1,5-pentanediol from THFA under mild conditions. We elucidate the key role of the La(OH)3 phase, the basic sites and the Nin+-O-La3+ structure of the catalysts in promoting the selective hydrogenolysis and ring opening of THFA. We also demonstrate that the co-dehydrogenation of secondary alcohols enables lower reaction pressure and longer catalyst lifetime. Our work provides a sustainable and environmentally benign approach for producing 1,5-pentanediol from biomass-based furfural and its derivatives, which has potential applications in polymer synthesis and green chemistry." @default.
- W4385392014 created "2023-07-30" @default.
- W4385392014 creator A5017869126 @default.
- W4385392014 creator A5032263182 @default.
- W4385392014 creator A5054380581 @default.
- W4385392014 creator A5058040690 @default.
- W4385392014 creator A5064680400 @default.
- W4385392014 creator A5087327631 @default.
- W4385392014 creator A5088809185 @default.
- W4385392014 date "2023-12-01" @default.
- W4385392014 modified "2023-09-30" @default.
- W4385392014 title "Selective and efficient production of 1,5-pentanediol from tetrahydrofurfuryl alcohol using Ni-La(OH)3 catalysts" @default.
- W4385392014 cites W1542749645 @default.
- W4385392014 cites W1967213958 @default.
- W4385392014 cites W1968316906 @default.
- W4385392014 cites W1981986998 @default.
- W4385392014 cites W1983495481 @default.
- W4385392014 cites W1987995132 @default.
- W4385392014 cites W1997278403 @default.
- W4385392014 cites W2002529545 @default.
- W4385392014 cites W2005164624 @default.
- W4385392014 cites W2015144962 @default.
- W4385392014 cites W2017742383 @default.
- W4385392014 cites W2024964880 @default.
- W4385392014 cites W2042372302 @default.
- W4385392014 cites W2052436012 @default.
- W4385392014 cites W2060068545 @default.
- W4385392014 cites W2061662557 @default.
- W4385392014 cites W2074738712 @default.
- W4385392014 cites W2130971948 @default.
- W4385392014 cites W2292051459 @default.
- W4385392014 cites W2313993625 @default.
- W4385392014 cites W2317704676 @default.
- W4385392014 cites W2320034291 @default.
- W4385392014 cites W2329301016 @default.
- W4385392014 cites W2538521316 @default.
- W4385392014 cites W2574560218 @default.
- W4385392014 cites W2591394980 @default.
- W4385392014 cites W2605674726 @default.
- W4385392014 cites W2607236215 @default.
- W4385392014 cites W2622929106 @default.
- W4385392014 cites W2775464206 @default.
- W4385392014 cites W2788196444 @default.
- W4385392014 cites W2891030125 @default.
- W4385392014 cites W2894326237 @default.
- W4385392014 cites W2905216040 @default.
- W4385392014 cites W2984804082 @default.
- W4385392014 cites W2986356887 @default.
- W4385392014 cites W3020041361 @default.
- W4385392014 cites W3083507777 @default.
- W4385392014 cites W3124674362 @default.
- W4385392014 cites W3126776869 @default.
- W4385392014 cites W3198637458 @default.
- W4385392014 cites W4206755019 @default.
- W4385392014 cites W4220734898 @default.
- W4385392014 cites W4223519922 @default.
- W4385392014 cites W4226172078 @default.
- W4385392014 cites W4285607062 @default.
- W4385392014 cites W4296121077 @default.
- W4385392014 cites W4321178718 @default.
- W4385392014 doi "https://doi.org/10.1016/j.fuel.2023.129312" @default.
- W4385392014 hasPublicationYear "2023" @default.
- W4385392014 type Work @default.
- W4385392014 citedByCount "0" @default.
- W4385392014 crossrefType "journal-article" @default.
- W4385392014 hasAuthorship W4385392014A5017869126 @default.
- W4385392014 hasAuthorship W4385392014A5032263182 @default.
- W4385392014 hasAuthorship W4385392014A5054380581 @default.
- W4385392014 hasAuthorship W4385392014A5058040690 @default.
- W4385392014 hasAuthorship W4385392014A5064680400 @default.
- W4385392014 hasAuthorship W4385392014A5087327631 @default.
- W4385392014 hasAuthorship W4385392014A5088809185 @default.
- W4385392014 hasConcept C118792377 @default.
- W4385392014 hasConcept C119889771 @default.
- W4385392014 hasConcept C134121241 @default.
- W4385392014 hasConcept C161790260 @default.
- W4385392014 hasConcept C178790620 @default.
- W4385392014 hasConcept C181886296 @default.
- W4385392014 hasConcept C185592680 @default.
- W4385392014 hasConcept C191897082 @default.
- W4385392014 hasConcept C192562407 @default.
- W4385392014 hasConcept C2779719330 @default.
- W4385392014 hasConcept C2781066024 @default.
- W4385392014 hasConcept C94412978 @default.
- W4385392014 hasConceptScore W4385392014C118792377 @default.
- W4385392014 hasConceptScore W4385392014C119889771 @default.
- W4385392014 hasConceptScore W4385392014C134121241 @default.
- W4385392014 hasConceptScore W4385392014C161790260 @default.
- W4385392014 hasConceptScore W4385392014C178790620 @default.
- W4385392014 hasConceptScore W4385392014C181886296 @default.
- W4385392014 hasConceptScore W4385392014C185592680 @default.
- W4385392014 hasConceptScore W4385392014C191897082 @default.
- W4385392014 hasConceptScore W4385392014C192562407 @default.
- W4385392014 hasConceptScore W4385392014C2779719330 @default.
- W4385392014 hasConceptScore W4385392014C2781066024 @default.
- W4385392014 hasConceptScore W4385392014C94412978 @default.
- W4385392014 hasLocation W43853920141 @default.
- W4385392014 hasOpenAccess W4385392014 @default.