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- W4385392070 abstract "Na-ion battery is regarded as the most promising battery chemistry for the post Li-ion battery generation. Unlike Li-ion batteries, Na-ion batteries, due to the intrinsic instabilities, are rarely studied using electrochemical impedance spectroscopy to inspect the electrode kinetics within. Here, we combine the electrolyte-dependent Na metal labeling and distribution function of relaxation time analysis to readily deconvolute the conventional Nyquist spectrum of Na/NaCrO2 cells into individual electrode processes. Utilizing the corresponding equivalent circuit model with physical implications, the performance-limiting kinetics of Na/NaCrO2 cells with the typical ester-based electrolyte, PC/FEC, and ether-based one, diglyme, are precisely identified. Given the sluggish interference generated at the Na metal counter electrode with PC/FEC electrolyte, proper ether-based electrolytes are recommended to be adopted in the future validation of potential materials for Na-ion battery studies." @default.
- W4385392070 created "2023-07-30" @default.
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- W4385392070 date "2023-10-01" @default.
- W4385392070 modified "2023-10-02" @default.
- W4385392070 title "Deconvolution of the electrochemical impedance of Na/NaCrO2 cells with ester- and ether-based electrolytes" @default.
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- W4385392070 doi "https://doi.org/10.1016/j.jpowsour.2023.233465" @default.
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