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- W4385407795 abstract "Abstract High quantum yield triplets, populated by initially prepared excited singlets, are desired for various energy conversion schemes in solid working compositions like porous MOFs. However, a large disparity in the distribution of the excitonic center of mass, singlet‐triplet intersystem crossing (ISC) in such assemblies is inhibited, so much so that a carboxy‐coordinated zirconium heavy metal ion cannot effectively facilitate the ISC through spin‐orbit coupling. Circumventing this sluggish ISC, singlet fission (SF) is explored as a viable route to generating triplets in solution‐stable MOFs. Efficient SF is achieved through a high degree of interchromophoric coupling that facilitates electron super‐exchange to generate triplet pairs. Here we show that a predesigned chromophoric linker with extremely poor ISC efficiency ( k ISC ) but form triplets in MOF in contrast to the frameworks that are built from linkers with sizable k ISC but . This work opens a new photophysical and photochemical avenue in MOF chemistry and utility in energy conversion schemes." @default.
- W4385407795 created "2023-08-01" @default.
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- W4385407795 date "2023-08-08" @default.
- W4385407795 modified "2023-09-27" @default.
- W4385407795 title "Triplet Generation Through Singlet Fission in Metal‐Organic Framework: An Alternative Route to Inefficient Singlet‐Triplet Intersystem Crossing" @default.
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- W4385407795 doi "https://doi.org/10.1002/anie.202305323" @default.
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