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- W4385421563 abstract "Poly(methylmethacrylate-co-methacrylic acid) (PMMA-co-MAA) polymers were prepared via cobalt-mediated free radical copolymerization and were characterized after synthesis. The synthesis led to a 98.5% conversion and a final ratio between the two units, MMA/MAA, was equal to 63:37 mol%. PMMA-co-MAA was then used as a matrix for cellulose-based nanocomposites to tailor filler compatibility, thanks to the presence of carboxylic groups capable of generating strong H-bonds with the cellulose surface. Cellulose nanofibers (CNFs) were dispersed using a solution with a mixture of two solvents to tailor compatibility of both the components. For this purpose, CNFs were successfully re-dispersed in methanol using the solvent exchange method and tetrahydrofuran/methanol mixtures at different ratios were used for the preparation of the films. Fully transparent films of PMMA-co-MAA + CNF were prepared up to 15 wt% of CNF with a good dispersion in the matrix. This dispersion state leads to the reinforcement of the polymethacrylate matrix, increasing its tensile strength whilst preserving optical transparency." @default.
- W4385421563 created "2023-08-01" @default.
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- W4385421563 date "2023-07-28" @default.
- W4385421563 modified "2023-10-18" @default.
- W4385421563 title "Dispersion of Cellulose Nanofibers in Methacrylate-Based Nanocomposites" @default.
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- W4385421563 doi "https://doi.org/10.3390/polym15153226" @default.
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