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- W4385454802 abstract "Photopolymerization represents an environmentally friendly polymerization technique due to the ability of solvent-free and room-temperature curing. However, industrially used resins are usually derived from fossil resources, inherently increasing the environmental impact of such materials. Herein, the preparation of sequential interpenetrating polymer networks (IPNs) with a high content of renewable carbon by means of free radical photopolymerization and thermal epoxy curing was investigated in detail. Therefore, poly(ethylene glycol) dimethacrylate was used as UV-curable monomers, and resorcinol diglycidyl ether and trimethylolpropane were polymerized via step-growth polyaddition. Before the fabrication of IPNs, the networks were evaluated separately regarding their reactivity by means of (photo)-differential scanning calorimetry and real-time near-infrared photorheology. A combination of both networks resulted in IPNs with superior (thermo)mechanical properties and the ability to 3D-print complex shapes via stereolithography." @default.
- W4385454802 created "2023-08-02" @default.
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- W4385454802 date "2023-08-01" @default.
- W4385454802 modified "2023-09-24" @default.
- W4385454802 title "Green Monomers for 3D Printing: Epoxy-Methacrylate Interpenetrating Polymer Networks as a Versatile Alternative for Toughness Enhancement in Additive Manufacturing" @default.
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- W4385454802 doi "https://doi.org/10.1021/acssuschemeng.3c02194" @default.
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