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- W4385475971 abstract "Herein, we reported an effective selective nucleophilic cyclization/cross-coupling cascade reaction of N-tosyl ortho-alkynylanilines and N-acyl ortho-alkynylanilines using Rh(COD)2BF4/tBuXantPhos as a catalyst. The present protocol features excellent chemo- and regioselectivity, high atom-economy, and a broad range of substrates. The mechanism studies indicated that the key to the success of this reaction is the powerful capacity of the rhodium catalyst to recognize the N-substituent group in the selective nucleophilic cyclization and selective alkyne insertion." @default.
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- W4385475971 date "2023-08-02" @default.
- W4385475971 modified "2023-10-15" @default.
- W4385475971 title "Rhodium-Catalyzed Selective Nucleophilic Cyclization/Cross-Coupling of Two <i>ortho</i>-Alkynylanilines Bearing Differential <i>N</i>-Substituents" @default.
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- W4385475971 doi "https://doi.org/10.1021/acs.orglett.3c02180" @default.
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