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- W4385495598 abstract "Abstract Passivation of the sulfur cathode by insulating lithium sulfide restricts the reversibility and sulfur utilization of Li−S batteries. 3D nucleation of Li 2 S enabled by radical conversion may significantly boost the redox kinetics. Electrolytes with high donor number (DN) solvents allow for tri‐sulfur (S 3 ⋅ − ) radicals as intermediates, however, the catastrophic reactivity of such solvents with Li anodes pose a great challenge for their practical application. Here, we propose the use of quaternary ammonium salts as electrolyte additives, which can preserve the partial high‐DN characteristics that trigger the S 3 ⋅ − radical pathway, and inhibit the growth of Li dendrites. Li−S batteries with tetrapropylammonium bromide (T3Br) electrolyte additive deliver the outstanding cycling stability (700 cycles at 1 C with a low‐capacity decay rate of 0.049 % per cycle), and high capacity under a lean electrolyte of 5 μL electrolyte mg sulfur −1 . This work opens a new avenue for the development of electrolyte additives for Li−S batteries." @default.
- W4385495598 created "2023-08-03" @default.
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- W4385495598 date "2023-08-09" @default.
- W4385495598 modified "2023-10-15" @default.
- W4385495598 title "A Radical Pathway and Stabilized Li Anode Enabled by Halide Quaternary Ammonium Electrolyte Additives for Lithium‐Sulfur Batteries" @default.
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- W4385495598 doi "https://doi.org/10.1002/ange.202309046" @default.
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