Matches in SemOpenAlex for { <https://semopenalex.org/work/W4385496489> ?p ?o ?g. }
- W4385496489 endingPage "106135" @default.
- W4385496489 startingPage "106135" @default.
- W4385496489 abstract "This work presents a new solution for the removal of mercury from petroleum condensate via hollow fiber membrane contactor (HFMC), which follows the principles and practices of solvent extraction. Results demonstrate that mercury can be successfully removed from petroleum condensate feed by the synergistic mixture solution of HCl and thiourea as extractant. Under equal circulating flow rates of 1.67 cm3 s−1 of feed and the synergistic extractant (0.5 mol dm−3 HCl and 1.5 mol dm−3 thiourea) at 323.15 K, the percentage of mercury removal reached 98.4%. The values of ∆H° (120 kJ mol−1), ∆S° (0.37 kJ mol−1) and ∆G° (−1.15 kJ mol−1) indicate that the reaction is endothermic, irreversible and spontaneous at 323.15 K, respectively. The results of Fourier-transform infrared spectroscopy (FTIR) confirm that mercury has been removed and is consistent with the obtained reaction mechanism from density functional theory (DFT). To describe the mass transport through HFMC, two mass transport mathematical models corresponding to reaction flux and diffusion flux are considered. The reaction flux model is seen to fit in well with the experimental results. The mass transfer coefficients in the membrane phase (km) and shell side (ks) are 7.45 × 10−6 cm s−1 and 2.09 × 10−5 cm s−1, respectively indicating that the mass transfer in the membrane phase is the controlling step." @default.
- W4385496489 created "2023-08-03" @default.
- W4385496489 creator A5003881377 @default.
- W4385496489 creator A5028502778 @default.
- W4385496489 creator A5033079657 @default.
- W4385496489 creator A5043924169 @default.
- W4385496489 creator A5087110753 @default.
- W4385496489 creator A5091820663 @default.
- W4385496489 date "2023-08-01" @default.
- W4385496489 modified "2023-09-27" @default.
- W4385496489 title "New upstream solution for mercury removal from petroleum condensate via HFMC: Thermodynamics, kinetics, DFT and mass transport" @default.
- W4385496489 cites W1616964321 @default.
- W4385496489 cites W1966450206 @default.
- W4385496489 cites W1971866563 @default.
- W4385496489 cites W1973107012 @default.
- W4385496489 cites W1978979839 @default.
- W4385496489 cites W1982384865 @default.
- W4385496489 cites W1982684863 @default.
- W4385496489 cites W1987029859 @default.
- W4385496489 cites W1998138858 @default.
- W4385496489 cites W1999354382 @default.
- W4385496489 cites W2007772088 @default.
- W4385496489 cites W2018968566 @default.
- W4385496489 cites W2019966299 @default.
- W4385496489 cites W2022610895 @default.
- W4385496489 cites W2022844135 @default.
- W4385496489 cites W2023185932 @default.
- W4385496489 cites W2025874251 @default.
- W4385496489 cites W2027932637 @default.
- W4385496489 cites W2028046413 @default.
- W4385496489 cites W2038149712 @default.
- W4385496489 cites W2046534885 @default.
- W4385496489 cites W2049200072 @default.
- W4385496489 cites W2053967901 @default.
- W4385496489 cites W2057381190 @default.
- W4385496489 cites W2059400499 @default.
- W4385496489 cites W2065413714 @default.
- W4385496489 cites W2066544032 @default.
- W4385496489 cites W2076174252 @default.
- W4385496489 cites W2077429682 @default.
- W4385496489 cites W2078002147 @default.
- W4385496489 cites W2081912616 @default.
- W4385496489 cites W2090079258 @default.
- W4385496489 cites W2094110612 @default.
- W4385496489 cites W2136042359 @default.
- W4385496489 cites W2148403685 @default.
- W4385496489 cites W2152783510 @default.
- W4385496489 cites W2158986184 @default.
- W4385496489 cites W2162747676 @default.
- W4385496489 cites W2322978958 @default.
- W4385496489 cites W2510152573 @default.
- W4385496489 cites W2605410921 @default.
- W4385496489 cites W2735688483 @default.
- W4385496489 cites W2769331892 @default.
- W4385496489 cites W2896087605 @default.
- W4385496489 cites W2900308369 @default.
- W4385496489 cites W2905826321 @default.
- W4385496489 cites W2952364843 @default.
- W4385496489 cites W2953361421 @default.
- W4385496489 cites W2956518403 @default.
- W4385496489 cites W2962288226 @default.
- W4385496489 cites W2967759213 @default.
- W4385496489 cites W2989419786 @default.
- W4385496489 cites W2991429692 @default.
- W4385496489 cites W3001011120 @default.
- W4385496489 cites W3001161140 @default.
- W4385496489 cites W3035781277 @default.
- W4385496489 cites W3042786001 @default.
- W4385496489 cites W3080433433 @default.
- W4385496489 cites W3120410209 @default.
- W4385496489 cites W3158129062 @default.
- W4385496489 cites W3164467136 @default.
- W4385496489 cites W4205858257 @default.
- W4385496489 cites W4221062230 @default.
- W4385496489 cites W4282001511 @default.
- W4385496489 cites W4307831580 @default.
- W4385496489 cites W4310012119 @default.
- W4385496489 cites W4322721707 @default.
- W4385496489 doi "https://doi.org/10.1016/j.hydromet.2023.106135" @default.
- W4385496489 hasPublicationYear "2023" @default.
- W4385496489 type Work @default.
- W4385496489 citedByCount "0" @default.
- W4385496489 crossrefType "journal-article" @default.
- W4385496489 hasAuthorship W4385496489A5003881377 @default.
- W4385496489 hasAuthorship W4385496489A5028502778 @default.
- W4385496489 hasAuthorship W4385496489A5033079657 @default.
- W4385496489 hasAuthorship W4385496489A5043924169 @default.
- W4385496489 hasAuthorship W4385496489A5087110753 @default.
- W4385496489 hasAuthorship W4385496489A5091820663 @default.
- W4385496489 hasConcept C113196181 @default.
- W4385496489 hasConcept C121332964 @default.
- W4385496489 hasConcept C127413603 @default.
- W4385496489 hasConcept C147789679 @default.
- W4385496489 hasConcept C150394285 @default.
- W4385496489 hasConcept C160892712 @default.
- W4385496489 hasConcept C179104552 @default.
- W4385496489 hasConcept C185592680 @default.
- W4385496489 hasConcept C199360897 @default.