FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4385514095> ?p ?o ?g. }

• W4385514095 endingPage "13155" @default.
• W4385514095 startingPage "13148" @default.
• W4385514095 abstract "Herein, we have successfully synthesized two rubidium antimony (III) oxalates, namely, Rb2Sb(C2O4)2.5(H2O)3 and RbSb2(C2O4)F5, utilizing a low-temperature hydrothermal method. These two compounds share a similar chemical composition, consisting of Sb3+ cations with active lone pair electrons, alkali metal Rb+ ions, and planar π-conjugated C2O42– anions. However, they exhibit different symmetries, Rb2Sb(C2O4)2.5(H2O)3 is centrosymmetric (CS), while RbSb2(C2O4)F5 is noncentrosymmetric (NCS), which should be caused by the presence of F– ions. Notably, the NCS compound, RbSb2(C2O4)F5, demonstrates a moderate second-harmonic generation (SHG) response, approximately 1.3 times that of KH2PO4 (KDP), and exhibits a large birefringence of 0.09 at 546 nm. These characteristics indicate that RbSb2(C2O4)F5 holds promising potential as a nonlinear optical material for ultraviolet (UV) applications. Detailed structural analysis and theoretical calculations confirm that the excellent optical properties arise from the synergistic effects between Sb3+ cations with SCALP and planar π-conjugated [C2O4]2– groups." @default.
• W4385514095 created "2023-08-04" @default.
• W4385514095 creator A5000025780 @default.
• W4385514095 creator A5001866617 @default.
• W4385514095 creator A5020527447 @default.
• W4385514095 creator A5022376939 @default.
• W4385514095 creator A5026179846 @default.
• W4385514095 creator A5029051499 @default.
• W4385514095 creator A5038113064 @default.
• W4385514095 creator A5053261704 @default.
• W4385514095 creator A5056496295 @default.
• W4385514095 creator A5068226184 @default.
• W4385514095 date "2023-08-02" @default.
• W4385514095 modified "2023-10-15" @default.
• W4385514095 title "Centrosymmetric Rb₂Sb(C₂O₄)_2.5(H₂O)₃ and Noncentrosymmetric RbSb₂(C₂O₄)F₅: Two Antimony (III) Oxalates as UV Optical Materials" @default.
• W4385514095 cites W1981368803 @default.
• W4385514095 cites W1995070176 @default.
• W4385514095 cites W2019951471 @default.
• W4385514095 cites W2035481899 @default.
• W4385514095 cites W2041893040 @default.
• W4385514095 cites W2074019256 @default.
• W4385514095 cites W2101741054 @default.
• W4385514095 cites W2131350133 @default.
• W4385514095 cites W2166244948 @default.
• W4385514095 cites W2166689829 @default.
• W4385514095 cites W2238024636 @default.
• W4385514095 cites W2327193384 @default.
• W4385514095 cites W2471047469 @default.
• W4385514095 cites W2507191050 @default.
• W4385514095 cites W2531207561 @default.
• W4385514095 cites W2562759326 @default.
• W4385514095 cites W2570867793 @default.
• W4385514095 cites W2626618128 @default.
• W4385514095 cites W2758205860 @default.
• W4385514095 cites W2786216765 @default.
• W4385514095 cites W2791582335 @default.
• W4385514095 cites W2792923754 @default.
• W4385514095 cites W2804720489 @default.
• W4385514095 cites W2885996913 @default.
• W4385514095 cites W2889511196 @default.
• W4385514095 cites W2907070987 @default.
• W4385514095 cites W2913135708 @default.
• W4385514095 cites W2915457575 @default.
• W4385514095 cites W2916098729 @default.
• W4385514095 cites W2949236199 @default.
• W4385514095 cites W2953013388 @default.
• W4385514095 cites W2970218151 @default.
• W4385514095 cites W2973126474 @default.
• W4385514095 cites W2974429747 @default.
• W4385514095 cites W3000689462 @default.
• W4385514095 cites W3005289250 @default.
• W4385514095 cites W3012215015 @default.
• W4385514095 cites W3014020848 @default.
• W4385514095 cites W3022973919 @default.
• W4385514095 cites W3044088242 @default.
• W4385514095 cites W3047547740 @default.
• W4385514095 cites W3048301180 @default.
• W4385514095 cites W3093748398 @default.
• W4385514095 cites W3109786458 @default.
• W4385514095 cites W3111165386 @default.
• W4385514095 cites W3139639734 @default.
• W4385514095 cites W3165316347 @default.
• W4385514095 cites W3199108260 @default.
• W4385514095 cites W3216541068 @default.
• W4385514095 cites W4206632430 @default.
• W4385514095 cites W4210949282 @default.
• W4385514095 cites W4225711421 @default.
• W4385514095 cites W4245688462 @default.
• W4385514095 cites W4253074633 @default.
• W4385514095 cites W4281754826 @default.
• W4385514095 cites W4284962624 @default.
• W4385514095 cites W4288034724 @default.
• W4385514095 cites W4317438714 @default.
• W4385514095 cites W4319863983 @default.
• W4385514095 cites W4322749497 @default.
• W4385514095 cites W4383375090 @default.
• W4385514095 doi "https://doi.org/10.1021/acs.inorgchem.3c02175" @default.
• W4385514095 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37532705" @default.
• W4385514095 hasPublicationYear "2023" @default.
• W4385514095 type Work @default.
• W4385514095 citedByCount "0" @default.
• W4385514095 crossrefType "journal-article" @default.
• W4385514095 hasAuthorship W4385514095A5000025780 @default.
• W4385514095 hasAuthorship W4385514095A5001866617 @default.
• W4385514095 hasAuthorship W4385514095A5020527447 @default.
• W4385514095 hasAuthorship W4385514095A5022376939 @default.
• W4385514095 hasAuthorship W4385514095A5026179846 @default.
• W4385514095 hasAuthorship W4385514095A5029051499 @default.
• W4385514095 hasAuthorship W4385514095A5038113064 @default.
• W4385514095 hasAuthorship W4385514095A5053261704 @default.
• W4385514095 hasAuthorship W4385514095A5056496295 @default.
• W4385514095 hasAuthorship W4385514095A5068226184 @default.
• W4385514095 hasConcept C115624301 @default.
• W4385514095 hasConcept C121332964 @default.
• W4385514095 hasConcept C127313418 @default.
• W4385514095 hasConcept C145148216 @default.
• W4385514095 hasConcept C156622251 @default.
• W4385514095 hasConcept C158622935 @default.

• next