Matches in SemOpenAlex for { <https://semopenalex.org/work/W4385514959> ?p ?o ?g. }
Showing items 1 to 75 of
75
with 100 items per page.
- W4385514959 abstract "The macrocyclic pro‐ligand [H4L][OTf]2, which contains four carboxamide functions and two conjugated pyridinium groups, is easily deprotonated by the weak base sodium acetate to give the corresponding neutral pro‐ligand [H2L]. Metalation of [H2L] with iron(II) chloride proceeds rapidly to form the macrocyclic complex, [FeIIICl(L)]. This is an effective catalyst for the oxidation of the organic dye orange II by hydrogen peroxide in aqueous solution and the kinetic parameters for this reaction have been determined. In striking contrast to an analogous iron‐TAML complex that contains two phenyl groups in place of the two pyridinium groups, [FeIIICl(L)] is a very active oxidation catalyst at pH 7 and is also highly stable towards acid promoted demetallation at pH 5 or above. The results show that the two pyridinium groups bring greatly enhanced catalytic properties to [FeIIICl(L)]." @default.
- W4385514959 created "2023-08-04" @default.
- W4385514959 creator A5052878527 @default.
- W4385514959 creator A5067190736 @default.
- W4385514959 creator A5071577572 @default.
- W4385514959 creator A5087798538 @default.
- W4385514959 date "2023-08-02" @default.
- W4385514959 modified "2023-10-18" @default.
- W4385514959 title "An Iron Macrocyclic Complex Containing Four “Hybrid” Pyridinium Amidate/Amidate N‐Donors as a Catalyst for Oxidations With Hydrogen Peroxide" @default.
- W4385514959 doi "https://doi.org/10.1002/chem.202301548" @default.
- W4385514959 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37532869" @default.
- W4385514959 hasPublicationYear "2023" @default.
- W4385514959 type Work @default.
- W4385514959 citedByCount "0" @default.
- W4385514959 crossrefType "journal-article" @default.
- W4385514959 hasAuthorship W4385514959A5052878527 @default.
- W4385514959 hasAuthorship W4385514959A5067190736 @default.
- W4385514959 hasAuthorship W4385514959A5071577572 @default.
- W4385514959 hasAuthorship W4385514959A5087798538 @default.
- W4385514959 hasBestOaLocation W43855149591 @default.
- W4385514959 hasConcept C116569031 @default.
- W4385514959 hasConcept C118629725 @default.
- W4385514959 hasConcept C134306372 @default.
- W4385514959 hasConcept C145148216 @default.
- W4385514959 hasConcept C155647269 @default.
- W4385514959 hasConcept C161790260 @default.
- W4385514959 hasConcept C170493617 @default.
- W4385514959 hasConcept C178790620 @default.
- W4385514959 hasConcept C179104552 @default.
- W4385514959 hasConcept C184651966 @default.
- W4385514959 hasConcept C185592680 @default.
- W4385514959 hasConcept C188027245 @default.
- W4385514959 hasConcept C2777221202 @default.
- W4385514959 hasConcept C2779432074 @default.
- W4385514959 hasConcept C32909587 @default.
- W4385514959 hasConcept C33923547 @default.
- W4385514959 hasConcept C42058472 @default.
- W4385514959 hasConcept C533411734 @default.
- W4385514959 hasConcept C55493867 @default.
- W4385514959 hasConceptScore W4385514959C116569031 @default.
- W4385514959 hasConceptScore W4385514959C118629725 @default.
- W4385514959 hasConceptScore W4385514959C134306372 @default.
- W4385514959 hasConceptScore W4385514959C145148216 @default.
- W4385514959 hasConceptScore W4385514959C155647269 @default.
- W4385514959 hasConceptScore W4385514959C161790260 @default.
- W4385514959 hasConceptScore W4385514959C170493617 @default.
- W4385514959 hasConceptScore W4385514959C178790620 @default.
- W4385514959 hasConceptScore W4385514959C179104552 @default.
- W4385514959 hasConceptScore W4385514959C184651966 @default.
- W4385514959 hasConceptScore W4385514959C185592680 @default.
- W4385514959 hasConceptScore W4385514959C188027245 @default.
- W4385514959 hasConceptScore W4385514959C2777221202 @default.
- W4385514959 hasConceptScore W4385514959C2779432074 @default.
- W4385514959 hasConceptScore W4385514959C32909587 @default.
- W4385514959 hasConceptScore W4385514959C33923547 @default.
- W4385514959 hasConceptScore W4385514959C42058472 @default.
- W4385514959 hasConceptScore W4385514959C533411734 @default.
- W4385514959 hasConceptScore W4385514959C55493867 @default.
- W4385514959 hasLocation W43855149591 @default.
- W4385514959 hasLocation W43855149592 @default.
- W4385514959 hasOpenAccess W4385514959 @default.
- W4385514959 hasPrimaryLocation W43855149591 @default.
- W4385514959 hasRelatedWork W1966375750 @default.
- W4385514959 hasRelatedWork W1971138541 @default.
- W4385514959 hasRelatedWork W1978122890 @default.
- W4385514959 hasRelatedWork W1979424755 @default.
- W4385514959 hasRelatedWork W1994137655 @default.
- W4385514959 hasRelatedWork W2322034987 @default.
- W4385514959 hasRelatedWork W2327347015 @default.
- W4385514959 hasRelatedWork W2481644108 @default.
- W4385514959 hasRelatedWork W2579222535 @default.
- W4385514959 hasRelatedWork W2945556674 @default.
- W4385514959 isParatext "false" @default.
- W4385514959 isRetracted "false" @default.
- W4385514959 workType "article" @default.