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• W4385515311 abstract "We present a rhodium-catalysed ring-opening reaction of heterobicyclic alkenes with indole and pyrrole nucleophiles, resulting in 1,2-disubstitued trans-dihydronaphthalene cores in up to a 95% yield as a single diastereomer. The Rh-catalysed reaction demonstrated tolerance for a broad scope of nucleophiles as well as various heterobicyclic alkenes. Notably, the reaction was successful with substrates that previously performed poorly or failed under iridium catalysis. This reaction is 100% atom-economic and offers C–C bond formation without prior functionalization of the coupling partners." @default.
• W4385515311 created "2023-08-04" @default.
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• W4385515311 date "2023-09-01" @default.
• W4385515311 modified "2023-10-05" @default.
• W4385515311 title "Rhodium-catalyzed ring-opening reactions of heterobicyclic alkenes with heteroarene nucleophiles" @default.
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• W4385515311 doi "https://doi.org/10.1016/j.tetlet.2023.154685" @default.
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