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- W4385564621 abstract "Different from the well-investigated enynes, transition-metal-catalyzed carbocyclization reactions of allenynes are more attractive as a result of the unique structure and versatile reactivity of allenes. Herein, we report the first cobalt-catalyzed highly chemo- and stereoselective arylative carbocyclization of 1,6-allenynes with arylboronic acids, affording five-membered carbocycles and heterocycles with moderate to high yields, broad substrate scope, and wide functional group compatibility. Moreover, several mechanistic experiments were conducted to gain insight into the reaction process." @default.
- W4385564621 created "2023-08-05" @default.
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- W4385564621 date "2023-08-04" @default.
- W4385564621 modified "2023-10-12" @default.
- W4385564621 title "Cobalt-Catalyzed Chemo- and Stereoselective Arylative Carbocyclization of 1,6-Allenynes" @default.
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- W4385564621 doi "https://doi.org/10.1021/acs.orglett.3c01958" @default.
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