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- W4385582859 abstract "Chemocatalytic of CO2 as a low-cost C1 feedstock to produce valuable fine chemicals was considered as a green and environmental approach. Among the reported strategy, the cyclization of o-phenylenediamines with CO2 is of great significance due to their broad application in the industry and medicine. Hence, we reported the switchable organocatalysts-catalyzed synthesis of benzimidazoles via cyclization of o-phenylenediamines with CO2 and hydrosilane as a hydrogen source under mild conditions (60 ℃, 0.5 MPa). It was found that imidazolium hydrogen carbonate ionic liquids ([CnCmIm][HCO3]) was not only used as recyclable organic pre-catalysts for N-heterocyclic carbenes, but also served as a multifunctional catalyst in which could activate o-phenylenediamines, CO2, and hydrosilane. So, up to 99% conversion of o-phenylenediamines could be achieved for 8 h at 60 ℃ and the reactivity of the catalyst remained nearly unchanged after three cycles. This protocol provides a feasible methodology for fixing CO2 into valuable benzimidazoles." @default.
- W4385582859 created "2023-08-05" @default.
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- W4385582859 date "2023-10-01" @default.
- W4385582859 modified "2023-10-09" @default.
- W4385582859 title "Switchable organocatalysts: Highly efficient reductive functionalization of CO2 to benzimidazoles under mild conditions" @default.
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- W4385582859 doi "https://doi.org/10.1016/j.jece.2023.110709" @default.
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