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- W4385587060 abstract "Single-event kinetic concept is applied to develop a reactor model to study the catalytic dewaxing on commercial Pt/ZSM-5 catalyst using n-hexadecane as feedstock. The shape-selectivity effects were included in the reaction network by suppressing the elementary steps involving either reactants and/or products that can be sterically hindered on the catalyst pores due to shape and size constraints. A total of 14 kinetic parameters have been estimated from experimental data for n-hexadecane hydroconversion taken from literature using an optimization framework. Finally, reactor simulations are carried out for different operating conditions and feedstock to check the consistency of the model and identify the main parameters affecting the reactor performance. The special feature of this approach is related to the independence of the kinetic parameters on the feedstock type, which allows using the same set of kinetic parameter values to describe the catalytic dewaxing of complex feedstocks such as diesel fuels." @default.
- W4385587060 created "2023-08-05" @default.
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- W4385587060 date "2023-01-01" @default.
- W4385587060 modified "2023-10-17" @default.
- W4385587060 title "Single-event kinetic modeling of catalytic dewaxing on commercial Pt/ZSM-5" @default.
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- W4385587060 doi "https://doi.org/10.1016/b978-0-12-823869-1.00006-5" @default.
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