Matches in SemOpenAlex for { <https://semopenalex.org/work/W4385623601> ?p ?o ?g. }
- W4385623601 abstract "Abstract The present work systematically investigates the hydrolysis mechanism of cyclic ketene acetal (CKA) monomers in detail and explores polymerization in water under organic solvent‐free and surfactant‐free conditions. To understand the effect of CKA structure on hydrolysis, the ring size of the monomers is varied from 5–8‐membered rings systematically and hydrolysis experiments are performed. In all cases, hydrolysis yields monoacetylated diol products. Deuterium and 17 O‐isotopic labeled experiments are carried out for 5‐ and 7‐membered‐(2‐methylene‐1,3‐dioxepane, MDO) CKAs to understand the reaction pathway. The experimental analysis from the reaction of CKA with water revealed that the increasing hydrophobicity from 5–8‐membered rings and the pH of the reaction medium play important roles in the order of reactivity. Density functional theory (DFT) and experimental studies demonstrated that basic reaction conditions have some control over the hydrolysis rate of CKA. Despite this progress, achieving controlled polymerization of CKA in water while suppressing hydrolysis remains challenge. Only up to 3 mol% CKA incorporation is attained in polyacrylate and polyacrylamide backbone via radical ring‐opening polymerization (rROP) of MDO and 8‐membered CKAs with 2‐hydroxyethyl acrylate (HEA) and acrylamide (AAm) in water. The results serve a proof of concept for advancing aqueous copolymerizations using CKA monomers." @default.
- W4385623601 created "2023-08-08" @default.
- W4385623601 creator A5009707798 @default.
- W4385623601 creator A5009734032 @default.
- W4385623601 creator A5014702474 @default.
- W4385623601 creator A5020060287 @default.
- W4385623601 creator A5034111515 @default.
- W4385623601 creator A5083546619 @default.
- W4385623601 date "2023-08-17" @default.
- W4385623601 modified "2023-10-09" @default.
- W4385623601 title "A Mechanistic Study on the Hydrolysis of Cyclic Ketene Acetal (CKA) and Proof of Concept of Polymerization in Water" @default.
- W4385623601 cites W1499071686 @default.
- W4385623601 cites W1689633449 @default.
- W4385623601 cites W1967882176 @default.
- W4385623601 cites W1978065383 @default.
- W4385623601 cites W1986025575 @default.
- W4385623601 cites W1987075015 @default.
- W4385623601 cites W1989935338 @default.
- W4385623601 cites W2018248204 @default.
- W4385623601 cites W2037570317 @default.
- W4385623601 cites W2049139866 @default.
- W4385623601 cites W2049682870 @default.
- W4385623601 cites W2052309937 @default.
- W4385623601 cites W2055327257 @default.
- W4385623601 cites W2060687945 @default.
- W4385623601 cites W2061439749 @default.
- W4385623601 cites W2073941521 @default.
- W4385623601 cites W2075188484 @default.
- W4385623601 cites W2139287008 @default.
- W4385623601 cites W2152653111 @default.
- W4385623601 cites W2156640963 @default.
- W4385623601 cites W2166333401 @default.
- W4385623601 cites W2321595519 @default.
- W4385623601 cites W2327407609 @default.
- W4385623601 cites W2483591154 @default.
- W4385623601 cites W2572929162 @default.
- W4385623601 cites W2600469750 @default.
- W4385623601 cites W2614347026 @default.
- W4385623601 cites W2769190466 @default.
- W4385623601 cites W2789959205 @default.
- W4385623601 cites W2900047384 @default.
- W4385623601 cites W2903602781 @default.
- W4385623601 cites W2951142173 @default.
- W4385623601 cites W2951446008 @default.
- W4385623601 cites W2967490718 @default.
- W4385623601 cites W3023913531 @default.
- W4385623601 cites W3024948138 @default.
- W4385623601 cites W3025796928 @default.
- W4385623601 cites W3027992216 @default.
- W4385623601 cites W3035844784 @default.
- W4385623601 cites W3080982949 @default.
- W4385623601 cites W3110095379 @default.
- W4385623601 cites W3128636800 @default.
- W4385623601 cites W3159461459 @default.
- W4385623601 cites W3202210807 @default.
- W4385623601 cites W4206541490 @default.
- W4385623601 cites W4211263050 @default.
- W4385623601 cites W4251091618 @default.
- W4385623601 cites W4281398536 @default.
- W4385623601 cites W4316022317 @default.
- W4385623601 cites W4323347620 @default.
- W4385623601 doi "https://doi.org/10.1002/macp.202300221" @default.
- W4385623601 hasPublicationYear "2023" @default.
- W4385623601 type Work @default.
- W4385623601 citedByCount "0" @default.
- W4385623601 crossrefType "journal-article" @default.
- W4385623601 hasAuthorship W4385623601A5009707798 @default.
- W4385623601 hasAuthorship W4385623601A5009734032 @default.
- W4385623601 hasAuthorship W4385623601A5014702474 @default.
- W4385623601 hasAuthorship W4385623601A5020060287 @default.
- W4385623601 hasAuthorship W4385623601A5034111515 @default.
- W4385623601 hasAuthorship W4385623601A5083546619 @default.
- W4385623601 hasConcept C142724271 @default.
- W4385623601 hasConcept C166940927 @default.
- W4385623601 hasConcept C178790620 @default.
- W4385623601 hasConcept C183882617 @default.
- W4385623601 hasConcept C184651966 @default.
- W4385623601 hasConcept C185592680 @default.
- W4385623601 hasConcept C188027245 @default.
- W4385623601 hasConcept C203897987 @default.
- W4385623601 hasConcept C204787440 @default.
- W4385623601 hasConcept C2776910235 @default.
- W4385623601 hasConcept C2777731525 @default.
- W4385623601 hasConcept C2778874822 @default.
- W4385623601 hasConcept C2779989194 @default.
- W4385623601 hasConcept C44228677 @default.
- W4385623601 hasConcept C521977710 @default.
- W4385623601 hasConcept C71924100 @default.
- W4385623601 hasConcept C94412978 @default.
- W4385623601 hasConceptScore W4385623601C142724271 @default.
- W4385623601 hasConceptScore W4385623601C166940927 @default.
- W4385623601 hasConceptScore W4385623601C178790620 @default.
- W4385623601 hasConceptScore W4385623601C183882617 @default.
- W4385623601 hasConceptScore W4385623601C184651966 @default.
- W4385623601 hasConceptScore W4385623601C185592680 @default.
- W4385623601 hasConceptScore W4385623601C188027245 @default.
- W4385623601 hasConceptScore W4385623601C203897987 @default.
- W4385623601 hasConceptScore W4385623601C204787440 @default.
- W4385623601 hasConceptScore W4385623601C2776910235 @default.
- W4385623601 hasConceptScore W4385623601C2777731525 @default.