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• W4385658625 abstract "We report the results of a computational investigation into fluoride binding by a series of pentavalent pnictogen Lewis acids: pnictogen pentahalides (PnX5), tetraphenyl pnictogeniums (PnPh4+), and triphenyl pnictogen tetrachlorocatecholates (PnPh3Cat). Activation strain and energy decomposition analyses of the Lewis adducts not only clearly delineate the electrostatic and orbital contributions to these acid–base interactions but also highlight the importance of Pauli repulsion and molecular flexibility in determining relative Lewis acidity among the pnictogens." @default.
• W4385658625 created "2023-08-09" @default.
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• W4385658625 date "2023-08-08" @default.
• W4385658625 modified "2023-09-25" @default.
• W4385658625 title "Analyzing Fluoride Binding by Group 15 Lewis Acids: Pnictogen Bonding in the Pentavalent State" @default.
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• W4385658625 doi "https://doi.org/10.1021/acs.inorgchem.3c01987" @default.
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• W4385658625 hasPublicationYear "2023" @default.
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