Matches in SemOpenAlex for { <https://semopenalex.org/work/W4385664628> ?p ?o ?g. }
- W4385664628 endingPage "126261" @default.
- W4385664628 startingPage "126261" @default.
- W4385664628 abstract "Recently, great interest has been in synthesizing polymers containing fluorine atoms. Fluorinated polymers exhibit high hydrophobicity, low surface energy, good thermal stability, excellent dielectric properties, low water absorption, and good chemical resistance. This work illustrates the synthesis, characterization, and properties of a new fluorinated aromatic polyester. Poly(fluoromandelic acid) (PFMA). PFMA is a new polymer with multiple fluorine atoms on the polymer chain. Simple heating of 4-fluoromandelic acid, without a solvent or a catalyst, under controlled conditions leads to poly(fluoromandelic acid). The reaction runs in the solid state by the elimination of water. The structure of the resulting poly(fluoromandelic acid) consists mainly of a polyester backbone decorated with p-fluorophenyl groups and has carboxyl and hydroxyl groups at the ends of the polymer chain. Mass spectrometry, solid-state 13C nuclear magnetic resonance (13C ss-NMR), liquid NMR, Fourier-transform infrared spectroscopy (FTIR), and Raman spectroscopy elucidated the polymer chain structure. The thermal stability of the polymer was also studied, and the melting point was determined from the differential scanning calorimetry. In the case of poly(fluoromandelic acid), the thermal conductivities and diffusivity were measured by the transient plane source (TPS) technique, also referred to as the Hot Disk method. The thermal conductivity measured at different temperatures will also be discussed in relation to the structure of the analyzed polymer as correlated with the crystallinity of the polymer structure determined by XRD diffraction. It was also shown that the new fluorinated aromatic polyester exhibited remarkable hydrophobicity." @default.
- W4385664628 created "2023-08-09" @default.
- W4385664628 creator A5005567217 @default.
- W4385664628 creator A5017810934 @default.
- W4385664628 creator A5037902644 @default.
- W4385664628 creator A5047078076 @default.
- W4385664628 creator A5058615604 @default.
- W4385664628 creator A5058973225 @default.
- W4385664628 creator A5071394333 @default.
- W4385664628 date "2023-09-01" @default.
- W4385664628 modified "2023-10-17" @default.
- W4385664628 title "Efficient chemical synthesis of new thermoplastic fluorinated aromatic polyester" @default.
- W4385664628 cites W1964640079 @default.
- W4385664628 cites W1967007012 @default.
- W4385664628 cites W1969764983 @default.
- W4385664628 cites W1972639583 @default.
- W4385664628 cites W1976804427 @default.
- W4385664628 cites W1989230717 @default.
- W4385664628 cites W2016582010 @default.
- W4385664628 cites W2023520398 @default.
- W4385664628 cites W2053007450 @default.
- W4385664628 cites W2056910563 @default.
- W4385664628 cites W2057961774 @default.
- W4385664628 cites W2059477392 @default.
- W4385664628 cites W2068023907 @default.
- W4385664628 cites W2084770795 @default.
- W4385664628 cites W2131238319 @default.
- W4385664628 cites W2142209097 @default.
- W4385664628 cites W2162882214 @default.
- W4385664628 cites W2268307240 @default.
- W4385664628 cites W2320146388 @default.
- W4385664628 cites W2470121329 @default.
- W4385664628 cites W2569141336 @default.
- W4385664628 cites W2589816650 @default.
- W4385664628 cites W2611432717 @default.
- W4385664628 cites W2617864720 @default.
- W4385664628 cites W2768924779 @default.
- W4385664628 cites W2787385365 @default.
- W4385664628 cites W2894939556 @default.
- W4385664628 cites W2900346600 @default.
- W4385664628 cites W2921949634 @default.
- W4385664628 cites W2965497785 @default.
- W4385664628 cites W2977328892 @default.
- W4385664628 cites W3008934362 @default.
- W4385664628 cites W3028015326 @default.
- W4385664628 cites W3049048672 @default.
- W4385664628 cites W3090499220 @default.
- W4385664628 cites W3101096399 @default.
- W4385664628 cites W3127365087 @default.
- W4385664628 cites W3177598949 @default.
- W4385664628 cites W3194597963 @default.
- W4385664628 cites W3211868226 @default.
- W4385664628 cites W4289668445 @default.
- W4385664628 cites W4307905471 @default.
- W4385664628 doi "https://doi.org/10.1016/j.polymer.2023.126261" @default.
- W4385664628 hasPublicationYear "2023" @default.
- W4385664628 type Work @default.
- W4385664628 citedByCount "0" @default.
- W4385664628 crossrefType "journal-article" @default.
- W4385664628 hasAuthorship W4385664628A5005567217 @default.
- W4385664628 hasAuthorship W4385664628A5017810934 @default.
- W4385664628 hasAuthorship W4385664628A5037902644 @default.
- W4385664628 hasAuthorship W4385664628A5047078076 @default.
- W4385664628 hasAuthorship W4385664628A5058615604 @default.
- W4385664628 hasAuthorship W4385664628A5058973225 @default.
- W4385664628 hasAuthorship W4385664628A5071394333 @default.
- W4385664628 hasConcept C119394753 @default.
- W4385664628 hasConcept C121332964 @default.
- W4385664628 hasConcept C127413603 @default.
- W4385664628 hasConcept C159985019 @default.
- W4385664628 hasConcept C160892712 @default.
- W4385664628 hasConcept C178790620 @default.
- W4385664628 hasConcept C185592680 @default.
- W4385664628 hasConcept C188027245 @default.
- W4385664628 hasConcept C192562407 @default.
- W4385664628 hasConcept C39519442 @default.
- W4385664628 hasConcept C42360764 @default.
- W4385664628 hasConcept C46275449 @default.
- W4385664628 hasConcept C521977710 @default.
- W4385664628 hasConcept C59061564 @default.
- W4385664628 hasConcept C97355855 @default.
- W4385664628 hasConceptScore W4385664628C119394753 @default.
- W4385664628 hasConceptScore W4385664628C121332964 @default.
- W4385664628 hasConceptScore W4385664628C127413603 @default.
- W4385664628 hasConceptScore W4385664628C159985019 @default.
- W4385664628 hasConceptScore W4385664628C160892712 @default.
- W4385664628 hasConceptScore W4385664628C178790620 @default.
- W4385664628 hasConceptScore W4385664628C185592680 @default.
- W4385664628 hasConceptScore W4385664628C188027245 @default.
- W4385664628 hasConceptScore W4385664628C192562407 @default.
- W4385664628 hasConceptScore W4385664628C39519442 @default.
- W4385664628 hasConceptScore W4385664628C42360764 @default.
- W4385664628 hasConceptScore W4385664628C46275449 @default.
- W4385664628 hasConceptScore W4385664628C521977710 @default.
- W4385664628 hasConceptScore W4385664628C59061564 @default.
- W4385664628 hasConceptScore W4385664628C97355855 @default.
- W4385664628 hasFunder F4320318622 @default.
- W4385664628 hasLocation W43856646281 @default.