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• W4385684893 abstract "The Mislow–Evans rearrangement was used as a key reaction to construct digitoxose-derived glycals. The same rearrangement was iteratively performed on di- and trisaccharides to form the digoxose glycal donor component present in the cardenolides digitoxin, digoxin, and gitoxin. The scalability of the trisaccharide synthesis was shown by performing the reactions on a multigram scale. Glycosylation reactions were also performed between the synthesized digoxin glycal donor and aglycons digoxigenin and gitoxigenin to synthesize novel cardenolide derivatives." @default.
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• W4385684893 date "2023-08-09" @default.
• W4385684893 modified "2023-09-26" @default.
• W4385684893 title "A Short Route to the Synthesis of Digoxose Trisaccharide Glycal Donor via Mislow–Evans Rearrangement" @default.
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• W4385684893 doi "https://doi.org/10.1021/acs.joc.3c01067" @default.
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