Matches in SemOpenAlex for { <https://semopenalex.org/work/W4385686009> ?p ?o ?g. }
- W4385686009 endingPage "12962" @default.
- W4385686009 startingPage "12949" @default.
- W4385686009 abstract "Herein, a novel continuous fixed-bed process for methacrolein (MAL) production via aldol condensation of formaldehyde with propionaldehyde over a sulfonic acid resin was developed, which exhibited high efficiency and remarkable catalytic stability. The influence of Brønsted acid strength and solvent permittivity on aldol reaction was revealed, and the optimal sulfonic acid resin (NKC-9) with suitable acid strength (H0 = 0.46) was identified. Meanwhile, the occupancy of water molecules on acid sites, which would lead to side reactions and catalyst deactivation, could be effectively inhibited through the construction of a liquid–solid catalytic system in non-polar media. The propionaldehyde conversion and MAL yield could reach up to 97.3 and 90.1% after optimization using the response surface method, respectively. Kinetic studies revealed that the surface reaction was the rate-limiting step with an activation energy of 57.1 kJ/mol. No deactivation behavior was observed for this kind of catalyst after 300 h on stream." @default.
- W4385686009 created "2023-08-10" @default.
- W4385686009 creator A5022246702 @default.
- W4385686009 creator A5030921116 @default.
- W4385686009 creator A5034291270 @default.
- W4385686009 creator A5046512219 @default.
- W4385686009 creator A5065039510 @default.
- W4385686009 creator A5089278692 @default.
- W4385686009 date "2023-08-09" @default.
- W4385686009 modified "2023-09-27" @default.
- W4385686009 title "Continuous Synthesis of Methacrolein over Sulfonic Acid Resin Catalysts: Unraveling the Effect of Acid Strength and Solvent Permittivity" @default.
- W4385686009 cites W1484263560 @default.
- W4385686009 cites W1992842235 @default.
- W4385686009 cites W1995264890 @default.
- W4385686009 cites W2008783080 @default.
- W4385686009 cites W2015549090 @default.
- W4385686009 cites W2018111037 @default.
- W4385686009 cites W2026671215 @default.
- W4385686009 cites W2040590904 @default.
- W4385686009 cites W2045397304 @default.
- W4385686009 cites W2101828012 @default.
- W4385686009 cites W2106172107 @default.
- W4385686009 cites W2136260455 @default.
- W4385686009 cites W2148765026 @default.
- W4385686009 cites W2325233242 @default.
- W4385686009 cites W2328093152 @default.
- W4385686009 cites W2329287291 @default.
- W4385686009 cites W2415363336 @default.
- W4385686009 cites W2463186501 @default.
- W4385686009 cites W2487894931 @default.
- W4385686009 cites W2587569060 @default.
- W4385686009 cites W2593562972 @default.
- W4385686009 cites W2755037120 @default.
- W4385686009 cites W2769242687 @default.
- W4385686009 cites W2769921791 @default.
- W4385686009 cites W2790344427 @default.
- W4385686009 cites W2896501772 @default.
- W4385686009 cites W2898436750 @default.
- W4385686009 cites W2899351082 @default.
- W4385686009 cites W2900847380 @default.
- W4385686009 cites W2901827856 @default.
- W4385686009 cites W2904038465 @default.
- W4385686009 cites W2908581546 @default.
- W4385686009 cites W2929343151 @default.
- W4385686009 cites W2944683476 @default.
- W4385686009 cites W2946804940 @default.
- W4385686009 cites W2948539667 @default.
- W4385686009 cites W2952886104 @default.
- W4385686009 cites W2990017179 @default.
- W4385686009 cites W2994229953 @default.
- W4385686009 cites W2995224148 @default.
- W4385686009 cites W2996058761 @default.
- W4385686009 cites W3001776037 @default.
- W4385686009 cites W3015607651 @default.
- W4385686009 cites W3016155384 @default.
- W4385686009 cites W3026812487 @default.
- W4385686009 cites W3048439949 @default.
- W4385686009 cites W3080624203 @default.
- W4385686009 cites W3083326903 @default.
- W4385686009 cites W3088657278 @default.
- W4385686009 cites W3116503686 @default.
- W4385686009 cites W3120084790 @default.
- W4385686009 cites W3129376735 @default.
- W4385686009 cites W3143811782 @default.
- W4385686009 cites W3149712520 @default.
- W4385686009 cites W3172964716 @default.
- W4385686009 cites W3186839011 @default.
- W4385686009 cites W3201475057 @default.
- W4385686009 cites W3203262763 @default.
- W4385686009 cites W3204351955 @default.
- W4385686009 cites W3206327319 @default.
- W4385686009 cites W3206548911 @default.
- W4385686009 cites W3209466743 @default.
- W4385686009 cites W3209678120 @default.
- W4385686009 cites W4200593110 @default.
- W4385686009 cites W4205158668 @default.
- W4385686009 cites W4205362126 @default.
- W4385686009 cites W4206370696 @default.
- W4385686009 cites W4211003326 @default.
- W4385686009 cites W4220788212 @default.
- W4385686009 cites W4220862592 @default.
- W4385686009 cites W4220975621 @default.
- W4385686009 cites W4225870268 @default.
- W4385686009 cites W4226238903 @default.
- W4385686009 cites W4229053934 @default.
- W4385686009 cites W4281387543 @default.
- W4385686009 cites W4281907463 @default.
- W4385686009 cites W4283817784 @default.
- W4385686009 cites W4286249788 @default.
- W4385686009 cites W4288078021 @default.
- W4385686009 cites W4309103253 @default.
- W4385686009 cites W4366249116 @default.
- W4385686009 cites W4377695317 @default.
- W4385686009 doi "https://doi.org/10.1021/acs.iecr.3c01550" @default.
- W4385686009 hasPublicationYear "2023" @default.
- W4385686009 type Work @default.
- W4385686009 citedByCount "0" @default.
- W4385686009 crossrefType "journal-article" @default.