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- W4385715397 endingPage "18246" @default.
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- W4385715397 abstract "The stereoselective total synthesis of structure 1 assigned to the macrolide natural product neaumycin B is reported in a 2.3% overall yield on 90 mg scale. The synthesis features a gram-scale nickel-catalyzed reductive cross-coupling/spiroketalization tactic to construct the spiroketal core of neaumycin B. The stereostructures of the C3–C6, C8–C14, and C20–C41 segments of synthetic neaumycin B were unambiguously verified by X-ray crystallography." @default.
- W4385715397 created "2023-08-11" @default.
- W4385715397 creator A5031080144 @default.
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- W4385715397 date "2023-08-10" @default.
- W4385715397 modified "2023-10-01" @default.
- W4385715397 title "Total Synthesis of the Reported Structure of Neaumycin B" @default.
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- W4385715397 doi "https://doi.org/10.1021/jacs.3c06573" @default.
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