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- W4385728972 abstract "Abstract Anti-Kasha’s emission in organic luminogens has attracted many attentions since its discovery. However, only limited examples of anti-Kasha rule have been reported and anti-Kasha triplet energy transfer (ET) is even less-touched. This work provided an efficient strategy to realize excitation wavelength dependent (Ex-De) afterglow in a host-guest system benefiting from anti-Kasha rule. Host has almost imperceptible RTP upon 365 nm excitation and guest is totally RTP inactive, while the doping system exhibits Ex-De afterglow with improved quantum yields. Anti-Kasha triplet ET process is demonstrated from the higher excited triplet state T 2 of host to the lowest excited singlet state S 1 of the aggregated/unimolecular state of guest . ET efficiency in the doping system could be tuned by adopting denser or looser intermolecular packing through simply changing processing methods. The strategy of anti-Kasha triplet ET endows doping system with multiple stimuli-responsive properties, including Ex-De afterglow, mechano- and thermal-triggered afterglow behavior. Corresponding applications are also realized in multiple information anti-counterfeiting and display." @default.
- W4385728972 created "2023-08-11" @default.
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- W4385728972 date "2023-08-08" @default.
- W4385728972 modified "2023-09-27" @default.
- W4385728972 title "Anti-Kasha Triplet Energy Transfer: Excitation Wavelength Dependent Persistent Luminescence from Host-Guest Doping Systems" @default.
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- W4385728972 doi "https://doi.org/10.21203/rs.3.rs-3198725/v1" @default.
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