FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4385759144> ?p ?o ?g. }

• W4385759144 endingPage "12281" @default.
• W4385759144 startingPage "12271" @default.
• W4385759144 abstract "In energetic materials research, energetic coordination compounds (ECCs) have received much attention due to their high thermal stability and insensitivity to mechanical stimuli. The energetic characteristics of ECCs can be modified by combining various metal cations, potent anions, and ligands. In this study, we have synthesized two energetic ligands, 5-(4-nitro-1H-pyrazol-3-yl)-1H-1,2,4-triazol-3-amine (NPTA) and (Z)-N-(5-(4-nitro-1H-pyrazol-3-yl)-2,4-dihydro-3H-1,2,4-triazol-3-ylidene)nitramide (NPTN), from a commercially viable starting material and reacted them with nitrate salts of various 3d metals (e.g., Ni, Co, Zn) to obtain six new ECCs, [Ni(NPTA)(H2O)3]2·2NO3 (1), [Co(NPTA)(H2O)3]2·2NO3 (2), [Zn(NPTA)(H2O)3]2·2NO3 (3), [Ni(NPTN)(H2O)3]2 (4), [Co(NPTN)(H2O)3]2 (5), and [Zn(NPTN)(H2O)3]2 (6) under ambient conditions. All the newly prepared ECCs were characterised through PXRD, IR, SEM, and TGA-DSC analysis. Furthermore, single crystal analysis proved that 1-6 are dimeric complexes. Moreover, 1-6 show excellent density ranges from 1.94 to 2.06 g cm-3 and remarkable thermal stability (216-352 °C), and are highly insensitive towards impact (>40 J) and friction (>360 N), describing their potential as high performing energetic materials. All the ECCs revealed good enthalpy of combustion (-6.3 to -9.94 kJ g-1). Additionally, the Hirshfeld surface and 2D fingerprint analysis were used to understand the close contact of atoms within the molecules. High crystal densities, thermal stabilities and low sensitivities make the synthesized ECCs interesting for further studies and potential applications as safe high-energy dense materials." @default.
• W4385759144 created "2023-08-12" @default.
• W4385759144 creator A5001622113 @default.
• W4385759144 creator A5006994057 @default.
• W4385759144 creator A5012505927 @default.
• W4385759144 creator A5047803751 @default.
• W4385759144 date "2023-01-01" @default.
• W4385759144 modified "2023-10-17" @default.
• W4385759144 title "Energetic coordination compounds: self-assembled from the nitrogen-rich energetic C–C bonded pyrazoles and triazoles" @default.
• W4385759144 cites W2083016113 @default.
• W4385759144 cites W2256582667 @default.
• W4385759144 cites W2257008141 @default.
• W4385759144 cites W2790187743 @default.
• W4385759144 cites W2928438849 @default.
• W4385759144 cites W2972824863 @default.
• W4385759144 cites W2980283193 @default.
• W4385759144 cites W3011905587 @default.
• W4385759144 cites W3037164971 @default.
• W4385759144 cites W3109969137 @default.
• W4385759144 cites W3111013609 @default.
• W4385759144 cites W3159829212 @default.
• W4385759144 cites W3205563809 @default.
• W4385759144 cites W3209908741 @default.
• W4385759144 cites W4210741688 @default.
• W4385759144 cites W4229024764 @default.
• W4385759144 cites W4283831569 @default.
• W4385759144 cites W4285179512 @default.
• W4385759144 cites W4289861250 @default.
• W4385759144 cites W4307302170 @default.
• W4385759144 cites W4312759242 @default.
• W4385759144 cites W4317438686 @default.
• W4385759144 cites W4319655587 @default.
• W4385759144 cites W4323907071 @default.
• W4385759144 cites W4324045114 @default.
• W4385759144 doi "https://doi.org/10.1039/d3dt02410e" @default.
• W4385759144 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37609759" @default.
• W4385759144 hasPublicationYear "2023" @default.
• W4385759144 type Work @default.
• W4385759144 citedByCount "1" @default.
• W4385759144 crossrefType "journal-article" @default.
• W4385759144 hasAuthorship W4385759144A5001622113 @default.
• W4385759144 hasAuthorship W4385759144A5006994057 @default.
• W4385759144 hasAuthorship W4385759144A5012505927 @default.
• W4385759144 hasAuthorship W4385759144A5047803751 @default.
• W4385759144 hasConcept C121332964 @default.
• W4385759144 hasConcept C129446986 @default.
• W4385759144 hasConcept C131779359 @default.
• W4385759144 hasConcept C13965031 @default.
• W4385759144 hasConcept C153294291 @default.
• W4385759144 hasConcept C154238967 @default.
• W4385759144 hasConcept C178790620 @default.
• W4385759144 hasConcept C185039092 @default.
• W4385759144 hasConcept C185592680 @default.
• W4385759144 hasConcept C204530211 @default.
• W4385759144 hasConcept C2778026756 @default.
• W4385759144 hasConcept C2780263894 @default.
• W4385759144 hasConcept C2780639532 @default.
• W4385759144 hasConcept C537208039 @default.
• W4385759144 hasConcept C544153396 @default.
• W4385759144 hasConcept C59061564 @default.
• W4385759144 hasConcept C68913812 @default.
• W4385759144 hasConcept C8010536 @default.
• W4385759144 hasConceptScore W4385759144C121332964 @default.
• W4385759144 hasConceptScore W4385759144C129446986 @default.
• W4385759144 hasConceptScore W4385759144C131779359 @default.
• W4385759144 hasConceptScore W4385759144C13965031 @default.
• W4385759144 hasConceptScore W4385759144C153294291 @default.
• W4385759144 hasConceptScore W4385759144C154238967 @default.
• W4385759144 hasConceptScore W4385759144C178790620 @default.
• W4385759144 hasConceptScore W4385759144C185039092 @default.
• W4385759144 hasConceptScore W4385759144C185592680 @default.
• W4385759144 hasConceptScore W4385759144C204530211 @default.
• W4385759144 hasConceptScore W4385759144C2778026756 @default.
• W4385759144 hasConceptScore W4385759144C2780263894 @default.
• W4385759144 hasConceptScore W4385759144C2780639532 @default.
• W4385759144 hasConceptScore W4385759144C537208039 @default.
• W4385759144 hasConceptScore W4385759144C544153396 @default.
• W4385759144 hasConceptScore W4385759144C59061564 @default.
• W4385759144 hasConceptScore W4385759144C68913812 @default.
• W4385759144 hasConceptScore W4385759144C8010536 @default.
• W4385759144 hasFunder F4320320712 @default.
• W4385759144 hasFunder F4320320721 @default.
• W4385759144 hasFunder F4320334771 @default.
• W4385759144 hasIssue "35" @default.
• W4385759144 hasLocation W43857591441 @default.
• W4385759144 hasLocation W43857591442 @default.
• W4385759144 hasOpenAccess W4385759144 @default.
• W4385759144 hasPrimaryLocation W43857591441 @default.
• W4385759144 hasRelatedWork W1988522370 @default.
• W4385759144 hasRelatedWork W2014734772 @default.
• W4385759144 hasRelatedWork W2101329032 @default.
• W4385759144 hasRelatedWork W2166175558 @default.
• W4385759144 hasRelatedWork W2317907472 @default.
• W4385759144 hasRelatedWork W2796673923 @default.
• W4385759144 hasRelatedWork W2950644762 @default.
• W4385759144 hasRelatedWork W4232449564 @default.
• W4385759144 hasRelatedWork W4255433949 @default.
• W4385759144 hasRelatedWork W2561856895 @default.

• next