Matches in SemOpenAlex for { <https://semopenalex.org/work/W4385778840> ?p ?o ?g. }
- W4385778840 abstract "Abstract Deazaflavins are important analogues of the naturally occurring flavins: riboflavin, flavin mononucleotide (FMN), and flavin adenine dinucleotide (FAD). The use of 5‐deazaflavin as a replacement coenzyme in a number of flavoproteins has proven particularly valuable in unraveling and manipulating their reaction mechanisms. It was frequently reported that one‐electron‐transfer reactions in flavoproteins are impeded with 5‐deazaflavin as the cofactor. Based on these findings, it was concluded that the 5‐deazaflavin radical is significantly less stable compared to the respective flavin semiquinone and quickly re‐oxidizes or undergoes disproportionation. The long‐standing paradigm of 5‐deazaflavin being solely a two‐electron/hydride acceptor/donor—“a nicotinamide in flavin clothing”—needs to be re‐evaluated now with the indirect observation of a one‐electron‐reduced (paramagnetic) species using photochemically induced dynamic nuclear polarization (photo‐CIDNP) 1 H nuclear magnetic resonance (NMR) under biologically relevant conditions." @default.
- W4385778840 created "2023-08-13" @default.
- W4385778840 creator A5006304159 @default.
- W4385778840 creator A5027171030 @default.
- W4385778840 creator A5060786264 @default.
- W4385778840 creator A5062397730 @default.
- W4385778840 creator A5068798153 @default.
- W4385778840 creator A5074880525 @default.
- W4385778840 date "2023-09-15" @default.
- W4385778840 modified "2023-10-18" @default.
- W4385778840 title "Expanding Reaction Horizons: Evidence of the 5‐Deazaflavin Radical Through Photochemically Induced Dynamic Nuclear Polarization" @default.
- W4385778840 cites W1562718633 @default.
- W4385778840 cites W1598276635 @default.
- W4385778840 cites W185038430 @default.
- W4385778840 cites W1964243154 @default.
- W4385778840 cites W1977211749 @default.
- W4385778840 cites W1977776302 @default.
- W4385778840 cites W1978971052 @default.
- W4385778840 cites W1998802530 @default.
- W4385778840 cites W1998820908 @default.
- W4385778840 cites W2000288572 @default.
- W4385778840 cites W2000464836 @default.
- W4385778840 cites W2005026952 @default.
- W4385778840 cites W2016038127 @default.
- W4385778840 cites W2027357772 @default.
- W4385778840 cites W2038909986 @default.
- W4385778840 cites W2040489365 @default.
- W4385778840 cites W204189053 @default.
- W4385778840 cites W2042059831 @default.
- W4385778840 cites W2052632383 @default.
- W4385778840 cites W2056919582 @default.
- W4385778840 cites W2058210956 @default.
- W4385778840 cites W2058848030 @default.
- W4385778840 cites W2065314019 @default.
- W4385778840 cites W2066584710 @default.
- W4385778840 cites W2067718414 @default.
- W4385778840 cites W2069764065 @default.
- W4385778840 cites W2074770586 @default.
- W4385778840 cites W2076420632 @default.
- W4385778840 cites W2076755375 @default.
- W4385778840 cites W2085222022 @default.
- W4385778840 cites W2087723352 @default.
- W4385778840 cites W2089521117 @default.
- W4385778840 cites W2089642610 @default.
- W4385778840 cites W2094667643 @default.
- W4385778840 cites W2110075655 @default.
- W4385778840 cites W2122247905 @default.
- W4385778840 cites W2148284063 @default.
- W4385778840 cites W2153048172 @default.
- W4385778840 cites W2161754368 @default.
- W4385778840 cites W2163089766 @default.
- W4385778840 cites W2168836416 @default.
- W4385778840 cites W2342699700 @default.
- W4385778840 cites W2343743473 @default.
- W4385778840 cites W2520057004 @default.
- W4385778840 cites W2557088319 @default.
- W4385778840 cites W2574186579 @default.
- W4385778840 cites W2724254330 @default.
- W4385778840 cites W2761047004 @default.
- W4385778840 cites W2782363629 @default.
- W4385778840 cites W2787206617 @default.
- W4385778840 cites W2799576800 @default.
- W4385778840 cites W2812127840 @default.
- W4385778840 cites W2884649540 @default.
- W4385778840 cites W2897531699 @default.
- W4385778840 cites W2902846983 @default.
- W4385778840 cites W2974583809 @default.
- W4385778840 cites W2995120264 @default.
- W4385778840 cites W2998946302 @default.
- W4385778840 cites W3036016487 @default.
- W4385778840 cites W3158144348 @default.
- W4385778840 cites W323683347 @default.
- W4385778840 cites W4220694746 @default.
- W4385778840 cites W4280642943 @default.
- W4385778840 cites W4281976567 @default.
- W4385778840 cites W60303150 @default.
- W4385778840 doi "https://doi.org/10.1002/anie.202309334" @default.
- W4385778840 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37571931" @default.
- W4385778840 hasPublicationYear "2023" @default.
- W4385778840 type Work @default.
- W4385778840 citedByCount "0" @default.
- W4385778840 crossrefType "journal-article" @default.
- W4385778840 hasAuthorship W4385778840A5006304159 @default.
- W4385778840 hasAuthorship W4385778840A5027171030 @default.
- W4385778840 hasAuthorship W4385778840A5060786264 @default.
- W4385778840 hasAuthorship W4385778840A5062397730 @default.
- W4385778840 hasAuthorship W4385778840A5068798153 @default.
- W4385778840 hasAuthorship W4385778840A5074880525 @default.
- W4385778840 hasBestOaLocation W43857788401 @default.
- W4385778840 hasConcept C139066938 @default.
- W4385778840 hasConcept C161790260 @default.
- W4385778840 hasConcept C17365422 @default.
- W4385778840 hasConcept C179104552 @default.
- W4385778840 hasConcept C181199279 @default.
- W4385778840 hasConcept C185592680 @default.
- W4385778840 hasConcept C197957613 @default.
- W4385778840 hasConcept C2775859393 @default.
- W4385778840 hasConcept C2776001701 @default.
- W4385778840 hasConcept C2776370595 @default.
- W4385778840 hasConcept C2777427158 @default.