Matches in SemOpenAlex for { <https://semopenalex.org/work/W4385786104> ?p ?o ?g. }
- W4385786104 endingPage "113440" @default.
- W4385786104 startingPage "113440" @default.
- W4385786104 abstract "Efficient Ru(II) catalysts with substituted aniline based ligands were synthesized having chemical formula [Ru(η6-p-cymene)Cl2(L1)] [Ru-1] and [Ru(η6-p-cymene)Cl2(L2)] [Ru-2] (where, L1 = 3,5-bis(trifluoromethyl)aniline and L2 = 3,4,5- trimethoxy aniline). The structural features of both the complexes were authenticated by ESI-MS, 1H and 13C NMR, FT-IR, elemental analyses, and single-crystal X-ray diffraction studies. Catalytic performance of both [Ru-1] and [Ru-2] was investigated for conversion of primary amine to secondary amine using alcohols under milder and solvent-free conditions and compared with the reported aniline-based Ru(II)-arene complex [Ru-3]. Among them, [Ru-1] could achieve 100% selectivity towards mono N-alkylated amines with > 99% conversion without formation of any imine derivatives. The results suggested that the lone pair of electrons of benzyl alcohol binds easily to the electron-deficient Ru(II) center of [Ru-1] catalyst making it more effective compared to electron-rich [Ru-2] and [Ru-3] catalysts. The catalytic performance of [Ru-1] demonstrates that it is one of the most active primary amine ligated Ru(II) based catalytic systems for N-alkylation of anilines under milder and solvent-free conditions." @default.
- W4385786104 created "2023-08-13" @default.
- W4385786104 creator A5008650576 @default.
- W4385786104 creator A5036311605 @default.
- W4385786104 creator A5038725810 @default.
- W4385786104 creator A5044233374 @default.
- W4385786104 creator A5081301889 @default.
- W4385786104 creator A5088478337 @default.
- W4385786104 date "2023-09-01" @default.
- W4385786104 modified "2023-10-18" @default.
- W4385786104 title "Highly active primary amine ligated Ru(II)-arene complexes as selective catalysts for solvent-free N-alkylation of Anilines" @default.
- W4385786104 cites W1511959369 @default.
- W4385786104 cites W1532684710 @default.
- W4385786104 cites W1967217503 @default.
- W4385786104 cites W1970845598 @default.
- W4385786104 cites W1977420451 @default.
- W4385786104 cites W1980591912 @default.
- W4385786104 cites W1983868152 @default.
- W4385786104 cites W1993976575 @default.
- W4385786104 cites W1997027171 @default.
- W4385786104 cites W1998580952 @default.
- W4385786104 cites W2003105464 @default.
- W4385786104 cites W2014877194 @default.
- W4385786104 cites W2023882099 @default.
- W4385786104 cites W2028257896 @default.
- W4385786104 cites W2030511515 @default.
- W4385786104 cites W2033430056 @default.
- W4385786104 cites W2033556576 @default.
- W4385786104 cites W2034274656 @default.
- W4385786104 cites W2040087440 @default.
- W4385786104 cites W2043437207 @default.
- W4385786104 cites W2045757382 @default.
- W4385786104 cites W2051543432 @default.
- W4385786104 cites W2057228724 @default.
- W4385786104 cites W2059205366 @default.
- W4385786104 cites W2063549773 @default.
- W4385786104 cites W2064280767 @default.
- W4385786104 cites W2064881372 @default.
- W4385786104 cites W2072444901 @default.
- W4385786104 cites W2076336288 @default.
- W4385786104 cites W2076878887 @default.
- W4385786104 cites W2076946397 @default.
- W4385786104 cites W2079442392 @default.
- W4385786104 cites W2084616510 @default.
- W4385786104 cites W2086492638 @default.
- W4385786104 cites W2095983630 @default.
- W4385786104 cites W2107306256 @default.
- W4385786104 cites W2115476655 @default.
- W4385786104 cites W2115573123 @default.
- W4385786104 cites W2130281103 @default.
- W4385786104 cites W2131350133 @default.
- W4385786104 cites W2140325839 @default.
- W4385786104 cites W2147633475 @default.
- W4385786104 cites W2149162439 @default.
- W4385786104 cites W2149180363 @default.
- W4385786104 cites W2150971186 @default.
- W4385786104 cites W2151363744 @default.
- W4385786104 cites W2166753704 @default.
- W4385786104 cites W2169146772 @default.
- W4385786104 cites W2171128578 @default.
- W4385786104 cites W2215008279 @default.
- W4385786104 cites W2228246836 @default.
- W4385786104 cites W2289688541 @default.
- W4385786104 cites W2299395869 @default.
- W4385786104 cites W2312232934 @default.
- W4385786104 cites W2312677766 @default.
- W4385786104 cites W2313202140 @default.
- W4385786104 cites W2314898765 @default.
- W4385786104 cites W2315873215 @default.
- W4385786104 cites W2316125765 @default.
- W4385786104 cites W2357946441 @default.
- W4385786104 cites W2409631731 @default.
- W4385786104 cites W2474395404 @default.
- W4385786104 cites W2508377337 @default.
- W4385786104 cites W2515376723 @default.
- W4385786104 cites W2528069760 @default.
- W4385786104 cites W2567162526 @default.
- W4385786104 cites W2603737829 @default.
- W4385786104 cites W2681819057 @default.
- W4385786104 cites W2727142809 @default.
- W4385786104 cites W2729663648 @default.
- W4385786104 cites W2744777949 @default.
- W4385786104 cites W2774172454 @default.
- W4385786104 cites W2791277418 @default.
- W4385786104 cites W2891423525 @default.
- W4385786104 cites W2895558745 @default.
- W4385786104 cites W2901392948 @default.
- W4385786104 cites W2906229268 @default.
- W4385786104 cites W2906444497 @default.
- W4385786104 cites W2941510656 @default.
- W4385786104 cites W2944281586 @default.
- W4385786104 cites W2950083190 @default.
- W4385786104 cites W2950351471 @default.
- W4385786104 cites W2951238012 @default.
- W4385786104 cites W2952344285 @default.
- W4385786104 cites W2953314151 @default.
- W4385786104 cites W2971123012 @default.
- W4385786104 cites W2981042605 @default.