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- W4385786229 abstract "The separation performance of a membrane mainly depends on its morphology. Casting solutions formed by different solvents have different membrane formation mechanisms, resulting in the formation of membrane with different morphology and pores. CA with/without CQDs was dissolved in various solvents, using water as non-solvent to prepare CA membrane through non-solvent induced phase separation (NIPS). The dynamic behavior of membrane formation was investigated using the dope viscosity, optical microscope observation of non-solvent penetration into the casting film, and light transmittance. However, the thermodynamic behavior was demonstrated by the phase diagram and FTIR-microscopy. CQDs addition and suitable solvents can tailor the physicochemical properties of membrane through its formation. When CQDs were added to different solvents dissolved CA dope, the surface porosity and pore size of the membranes increased while skin layer thickness decreased. In addition to viscosity, the kinetic behavior of membrane formation was also affected by the affinity between solvent and non-solvent. FTIR-microscopy revealed that the time required for phase separation of the 2P system was longer than that of the DMSO system. This is due to the higher viscosity of the 2P system." @default.
- W4385786229 created "2023-08-13" @default.
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- W4385786229 date "2023-09-01" @default.
- W4385786229 modified "2023-10-18" @default.
- W4385786229 title "Mechanism of membrane formation from mixing cellulose acetate and carbon quantum dots together in different solvents" @default.
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- W4385786229 doi "https://doi.org/10.1016/j.jtice.2023.105082" @default.
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