Matches in SemOpenAlex for { <https://semopenalex.org/work/W4385792208> ?p ?o ?g. }
- W4385792208 abstract "Abstract Water and other small molecules frequently coordinate within metal‐organic frameworks (MOFs). These coordinated molecules may actively engage in mass transfer, moving together with the transport molecules, but this phenomenon has yet to be examined. In this study, we explore a unique water transfer mechanism in UTSA‐280, where an incoming water molecule can displace a coordinated molecule for mass transfer. We refer to this process as the “knock‐off” mechanism. Despite UTSA‐280 possessing one‐dimensional channels, the knock‐off transport enables water movement along the other two axes, effectively simulating a pseudo‐three‐dimensional mass transfer. Even with a relatively narrow pore width, the knock‐off mechanism enables a high water flux in the UTSA‐280 membrane. The knock‐off mechanism also renders UTSA‐280 superior water/ethanol diffusion selectivity for pervaporation. To validate this unique mechanism, we conducted 1 H and 2 H solid‐state NMR on UTSA‐280 after the adsorption of deuterated water. We also derived potential energy diagrams from the density functional theory to gain atomic‐level insight into the knock‐off and the direct‐hopping mechanisms. The simulation findings reveal that the energy barrier of the knock‐off mechanism is marginally lower than the direct‐hopping pathway, implying its potential role in enhancing water diffusion in UTSA‐280." @default.
- W4385792208 created "2023-08-14" @default.
- W4385792208 creator A5003414479 @default.
- W4385792208 creator A5008346743 @default.
- W4385792208 creator A5016768374 @default.
- W4385792208 creator A5040784794 @default.
- W4385792208 creator A5057468033 @default.
- W4385792208 creator A5062393468 @default.
- W4385792208 creator A5074911937 @default.
- W4385792208 creator A5079450230 @default.
- W4385792208 creator A5080707196 @default.
- W4385792208 date "2023-08-22" @default.
- W4385792208 modified "2023-10-14" @default.
- W4385792208 title "Fast Water Transport in UTSA‐280 via a Knock‐Off Mechanism" @default.
- W4385792208 cites W1971987358 @default.
- W4385792208 cites W1973281366 @default.
- W4385792208 cites W1986382623 @default.
- W4385792208 cites W2006817072 @default.
- W4385792208 cites W2007661885 @default.
- W4385792208 cites W2011735387 @default.
- W4385792208 cites W2035519584 @default.
- W4385792208 cites W2066828315 @default.
- W4385792208 cites W2316918399 @default.
- W4385792208 cites W2430588013 @default.
- W4385792208 cites W2560055577 @default.
- W4385792208 cites W2752474087 @default.
- W4385792208 cites W2791194144 @default.
- W4385792208 cites W2898766504 @default.
- W4385792208 cites W2903003467 @default.
- W4385792208 cites W2914727966 @default.
- W4385792208 cites W2922796517 @default.
- W4385792208 cites W2942998504 @default.
- W4385792208 cites W2944519259 @default.
- W4385792208 cites W2949484779 @default.
- W4385792208 cites W2954033820 @default.
- W4385792208 cites W2954591269 @default.
- W4385792208 cites W2965968768 @default.
- W4385792208 cites W2970315737 @default.
- W4385792208 cites W2977837898 @default.
- W4385792208 cites W2979549542 @default.
- W4385792208 cites W2995502992 @default.
- W4385792208 cites W3004787932 @default.
- W4385792208 cites W3005232390 @default.
- W4385792208 cites W3025850918 @default.
- W4385792208 cites W3087015075 @default.
- W4385792208 cites W3090343756 @default.
- W4385792208 cites W3091894444 @default.
- W4385792208 cites W3097148738 @default.
- W4385792208 cites W3103915194 @default.
- W4385792208 cites W3110279475 @default.
- W4385792208 cites W3116184666 @default.
- W4385792208 cites W3188924947 @default.
- W4385792208 cites W3194365540 @default.
- W4385792208 cites W3195937070 @default.
- W4385792208 cites W3200571383 @default.
- W4385792208 cites W3215191911 @default.
- W4385792208 cites W3216863968 @default.
- W4385792208 cites W4200424960 @default.
- W4385792208 cites W4205544759 @default.
- W4385792208 cites W4206365940 @default.
- W4385792208 cites W4213003488 @default.
- W4385792208 cites W4220743245 @default.
- W4385792208 cites W4220982253 @default.
- W4385792208 cites W4293467434 @default.
- W4385792208 cites W4312211720 @default.
- W4385792208 cites W4313487883 @default.
- W4385792208 cites W4321374300 @default.
- W4385792208 cites W4361218386 @default.
- W4385792208 cites W4376457179 @default.
- W4385792208 cites W4377031099 @default.
- W4385792208 doi "https://doi.org/10.1002/ange.202309874" @default.
- W4385792208 hasPublicationYear "2023" @default.
- W4385792208 type Work @default.
- W4385792208 citedByCount "0" @default.
- W4385792208 crossrefType "journal-article" @default.
- W4385792208 hasAuthorship W4385792208A5003414479 @default.
- W4385792208 hasAuthorship W4385792208A5008346743 @default.
- W4385792208 hasAuthorship W4385792208A5016768374 @default.
- W4385792208 hasAuthorship W4385792208A5040784794 @default.
- W4385792208 hasAuthorship W4385792208A5057468033 @default.
- W4385792208 hasAuthorship W4385792208A5062393468 @default.
- W4385792208 hasAuthorship W4385792208A5074911937 @default.
- W4385792208 hasAuthorship W4385792208A5079450230 @default.
- W4385792208 hasAuthorship W4385792208A5080707196 @default.
- W4385792208 hasBestOaLocation W43857922081 @default.
- W4385792208 hasConcept C119621388 @default.
- W4385792208 hasConcept C121332964 @default.
- W4385792208 hasConcept C127413603 @default.
- W4385792208 hasConcept C147597530 @default.
- W4385792208 hasConcept C159467904 @default.
- W4385792208 hasConcept C171250308 @default.
- W4385792208 hasConcept C178790620 @default.
- W4385792208 hasConcept C185592680 @default.
- W4385792208 hasConcept C192562407 @default.
- W4385792208 hasConcept C2988574769 @default.
- W4385792208 hasConcept C2992163139 @default.
- W4385792208 hasConcept C32909587 @default.
- W4385792208 hasConcept C55493867 @default.
- W4385792208 hasConcept C59593255 @default.
- W4385792208 hasConcept C62520636 @default.