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- W4385798840 abstract "The reactions of beryllium halides with diphenyl beryllium were investigated in the N- and O-donor solvents NEt3 and THF, as well as in benzene and dichloromethane in the presence of the Lewis basic ligands THF, NEt3 and N-heterocyclic carbenes with various steric demand. In all cases the selective formation of heteroleptic beryllium Grignard compounds of the general formula [(L)1-2BePhX]1-2 (X = Cl, Br, I; L = C-, N-, O-donor ligand) was observed. The stability of these complexes was investigated computationally, while the differences between homo- and heteroleptic systems were also evaluated NMR spectroscopically and with single crystal X-ray diffraction. Mechanistic studies on the formation and speciation of these beryllium Grignard complexes in solution were performed." @default.
- W4385798840 created "2023-08-15" @default.
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- W4385798840 date "2023-09-27" @default.
- W4385798840 modified "2023-10-09" @default.
- W4385798840 title "A Preference for Heterolepticity ‐ <i>Schlenk</i> Type Equilibria in Organometallic Beryllium Systems" @default.
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- W4385798840 doi "https://doi.org/10.1002/chem.202302495" @default.
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- W4385798840 hasPublicationYear "2023" @default.
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