FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4385845105> ?p ?o ?g. }

• W4385845105 endingPage "24459" @default.
• W4385845105 startingPage "24450" @default.
• W4385845105 abstract "Developing cost-effective electrocatalysts using earth-abundant metal as an alternative to expensive precious metal catalyst remains a key challenge for researchers. Several strategies are being researched/tested for making low-cost transition metal complexes with controlled electron-density and coordination flexibility around the metal center to enhance their catalytic activity. Herein, we report a novel lutidine coordinated cobalt(ii) acetate complex [(3,5-lutidine)2Co(OAc)2(H2O)2] (1) as a promising electrocatalyst for oxygen evolution reaction (OER). Complex 1 was characterized by FT-IR, elemental analysis, and single crystal X-ray diffraction data. The structure optimization of complex 1 was also done using DFT calculation and the obtained geometrical parameters were found to be in good agreement with the parameters obtained from the solid state structure obtained through single crystal X-ray diffraction data. Further, the molecular electrostatic potential (MEP) maps analysis of complex 1 observed electron rich centers that were found to be in agreement with the solid-state structure. It was understood that the coordination of lutidine as a Lewis base and acetate moiety as a flexible ligand will provide more coordination flexibility around the metal center to facilitate the catalytic reaction. Further, the electron rich centers around metal center will also support the enhancement of their catalytic activity. Complex 1 shows impressive OER activity, even better than the state-of-the-art IrO2 catalyst, in terms of turnover frequency (TOF: 0.05) and onset potential (1.50 V vs. RHE). The TOF for complex 1 is two and half times higher, while the onset potential is ca. 20 mV lower, than the benchmark IrO2 catalyst studied under identical conditions." @default.
• W4385845105 created "2023-08-16" @default.
• W4385845105 creator A5019977052 @default.
• W4385845105 creator A5029114741 @default.
• W4385845105 creator A5055099874 @default.
• W4385845105 creator A5060695819 @default.
• W4385845105 creator A5065543730 @default.
• W4385845105 creator A5080668729 @default.
• W4385845105 creator A5086484718 @default.
• W4385845105 date "2023-01-01" @default.
• W4385845105 modified "2023-10-14" @default.
• W4385845105 title "A novel cobalt(<scp>ii</scp>) acetate complex bearing lutidine ligand: a promising electrocatalyst for oxygen evolution reaction" @default.
• W4385845105 cites W1981768663 @default.
• W4385845105 cites W2005262654 @default.
• W4385845105 cites W2033033166 @default.
• W4385845105 cites W2081768728 @default.
• W4385845105 cites W2085219791 @default.
• W4385845105 cites W2086090636 @default.
• W4385845105 cites W2104919283 @default.
• W4385845105 cites W2162091109 @default.
• W4385845105 cites W2163836591 @default.
• W4385845105 cites W2178282306 @default.
• W4385845105 cites W2270799384 @default.
• W4385845105 cites W2332386396 @default.
• W4385845105 cites W2333596353 @default.
• W4385845105 cites W2343044577 @default.
• W4385845105 cites W2417002281 @default.
• W4385845105 cites W2514157351 @default.
• W4385845105 cites W2534928601 @default.
• W4385845105 cites W2561624323 @default.
• W4385845105 cites W2611238512 @default.
• W4385845105 cites W2634438386 @default.
• W4385845105 cites W2692515715 @default.
• W4385845105 cites W2765468436 @default.
• W4385845105 cites W2790212269 @default.
• W4385845105 cites W2790413481 @default.
• W4385845105 cites W2794316902 @default.
• W4385845105 cites W2795193936 @default.
• W4385845105 cites W2801184875 @default.
• W4385845105 cites W2806584502 @default.
• W4385845105 cites W2849214161 @default.
• W4385845105 cites W2885492317 @default.
• W4385845105 cites W2903602303 @default.
• W4385845105 cites W2908788498 @default.
• W4385845105 cites W2934428761 @default.
• W4385845105 cites W2945411159 @default.
• W4385845105 cites W2946060694 @default.
• W4385845105 cites W2948624741 @default.
• W4385845105 cites W2986733246 @default.
• W4385845105 cites W2998284104 @default.
• W4385845105 cites W3006115260 @default.
• W4385845105 cites W3017633677 @default.
• W4385845105 cites W3032630518 @default.
• W4385845105 cites W3037423086 @default.
• W4385845105 cites W3048093250 @default.
• W4385845105 cites W3048891966 @default.
• W4385845105 cites W3092340025 @default.
• W4385845105 cites W3110895320 @default.
• W4385845105 cites W3128428175 @default.
• W4385845105 cites W3170097520 @default.
• W4385845105 cites W3196374844 @default.
• W4385845105 cites W3205278671 @default.
• W4385845105 cites W3209610210 @default.
• W4385845105 cites W3209821542 @default.
• W4385845105 cites W3217084130 @default.
• W4385845105 cites W4200537187 @default.
• W4385845105 cites W4214498497 @default.
• W4385845105 cites W4214732650 @default.
• W4385845105 cites W4220812778 @default.
• W4385845105 cites W4224863245 @default.
• W4385845105 cites W4251733299 @default.
• W4385845105 cites W4281662281 @default.
• W4385845105 cites W4288724742 @default.
• W4385845105 cites W4290672582 @default.
• W4385845105 cites W4297238440 @default.
• W4385845105 cites W4319065552 @default.
• W4385845105 cites W4323827627 @default.
• W4385845105 doi "https://doi.org/10.1039/d3ra04709a" @default.
• W4385845105 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37588977" @default.
• W4385845105 hasPublicationYear "2023" @default.
• W4385845105 type Work @default.
• W4385845105 citedByCount "0" @default.
• W4385845105 crossrefType "journal-article" @default.
• W4385845105 hasAuthorship W4385845105A5019977052 @default.
• W4385845105 hasAuthorship W4385845105A5029114741 @default.
• W4385845105 hasAuthorship W4385845105A5055099874 @default.
• W4385845105 hasAuthorship W4385845105A5060695819 @default.
• W4385845105 hasAuthorship W4385845105A5065543730 @default.
• W4385845105 hasAuthorship W4385845105A5080668729 @default.
• W4385845105 hasAuthorship W4385845105A5086484718 @default.
• W4385845105 hasBestOaLocation W43858451051 @default.
• W4385845105 hasConcept C106773901 @default.
• W4385845105 hasConcept C116569031 @default.
• W4385845105 hasConcept C135473242 @default.
• W4385845105 hasConcept C147789679 @default.
• W4385845105 hasConcept C161790260 @default.
• W4385845105 hasConcept C170493617 @default.
• W4385845105 hasConcept C17525397 @default.

• next