FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4385851763> ?p ?o ?g. }

• W4385851763 endingPage "13963" @default.
• W4385851763 startingPage "13953" @default.
• W4385851763 abstract "The actinide–halogen complexes (AnO2X42–, X = Cl, Br, and I) are the simplest and most representative compounds for studying the bonding nature of actinides with ligands. In this work, we attempted to synthesize the crystals of NpO2X42– (X = Cl, Br, and I). The crystals of NpO2Cl42– and NpO2Br42– were successfully synthesized, in which the structure of NpO2Br42– was obtained for the first time. The crystal of NpO2I42– could not be obtained due to the rapid reduction of Np(VI) to Np(V) by I–. The molecular structures of NpO2Cl42– and NpO2Br42– were characterized by single-crystal X-ray diffraction and infrared, Raman, and UV–Vis–NIR absorption spectroscopy. The complexes of NpO2X42– (X = Cl, Br, and I) were also investigated by density functional theory calculations, and the calculated vibration frequencies and absorption features were comparable to the experimental results. Both the experimental results and theoretical calculations demonstrate the strengthened Np–O bonds and the weakened Np–X bonds across the NpO2X42– series; however, the population analysis on the frontier molecular orbitals (MOs) of NpO2X42– indicates a slight reduction in the Np–O bonding covalency and an enhancement in the Np–X bonding covalency from NpO2Cl42– to NpO2I42–. Results in this work have enriched the crystal database of the AnO2X42– family and provided insights into the bonding nature in the actinide complexes with soft- and hard-donor ligands." @default.
• W4385851763 created "2023-08-17" @default.
• W4385851763 creator A5006748375 @default.
• W4385851763 creator A5020194359 @default.
• W4385851763 creator A5022160059 @default.
• W4385851763 creator A5038916444 @default.
• W4385851763 creator A5048379858 @default.
• W4385851763 creator A5056912735 @default.
• W4385851763 creator A5078130910 @default.
• W4385851763 creator A5080750465 @default.
• W4385851763 date "2023-08-16" @default.
• W4385851763 modified "2023-09-26" @default.
• W4385851763 title "Synthesis, Structure, and Theoretical Calculations on NpO₂Br₄^2–" @default.
• W4385851763 cites W1531476510 @default.
• W4385851763 cites W1647312040 @default.
• W4385851763 cites W1964327614 @default.
• W4385851763 cites W1966297712 @default.
• W4385851763 cites W1966909878 @default.
• W4385851763 cites W1968683348 @default.
• W4385851763 cites W1969451308 @default.
• W4385851763 cites W1971818787 @default.
• W4385851763 cites W1976828279 @default.
• W4385851763 cites W1983856916 @default.
• W4385851763 cites W1985047006 @default.
• W4385851763 cites W1986997462 @default.
• W4385851763 cites W1988091937 @default.
• W4385851763 cites W1997932034 @default.
• W4385851763 cites W2001816668 @default.
• W4385851763 cites W2005721262 @default.
• W4385851763 cites W2008187217 @default.
• W4385851763 cites W2011573012 @default.
• W4385851763 cites W2017460920 @default.
• W4385851763 cites W2023071471 @default.
• W4385851763 cites W2023271753 @default.
• W4385851763 cites W2028747545 @default.
• W4385851763 cites W2037883956 @default.
• W4385851763 cites W2040654649 @default.
• W4385851763 cites W2040770475 @default.
• W4385851763 cites W2042980554 @default.
• W4385851763 cites W2050476463 @default.
• W4385851763 cites W2052530292 @default.
• W4385851763 cites W2054494321 @default.
• W4385851763 cites W2056657488 @default.
• W4385851763 cites W2056961283 @default.
• W4385851763 cites W2059205366 @default.
• W4385851763 cites W2068474360 @default.
• W4385851763 cites W2069006374 @default.
• W4385851763 cites W2076370245 @default.
• W4385851763 cites W2077251376 @default.
• W4385851763 cites W2079881477 @default.
• W4385851763 cites W2081308950 @default.
• W4385851763 cites W2086288648 @default.
• W4385851763 cites W2091208014 @default.
• W4385851763 cites W2092157292 @default.
• W4385851763 cites W2098614082 @default.
• W4385851763 cites W2116373706 @default.
• W4385851763 cites W2117535842 @default.
• W4385851763 cites W2119547517 @default.
• W4385851763 cites W2131350133 @default.
• W4385851763 cites W2132525235 @default.
• W4385851763 cites W2143981217 @default.
• W4385851763 cites W2150345533 @default.
• W4385851763 cites W2151324716 @default.
• W4385851763 cites W2170449097 @default.
• W4385851763 cites W2182738981 @default.
• W4385851763 cites W2186588606 @default.
• W4385851763 cites W2319488692 @default.
• W4385851763 cites W2325899604 @default.
• W4385851763 cites W2735049531 @default.
• W4385851763 cites W2736103016 @default.
• W4385851763 cites W2792805395 @default.
• W4385851763 cites W2889247253 @default.
• W4385851763 cites W2908050872 @default.
• W4385851763 cites W2946033942 @default.
• W4385851763 cites W2950767240 @default.
• W4385851763 cites W2950812176 @default.
• W4385851763 cites W2960515713 @default.
• W4385851763 cites W3013651756 @default.
• W4385851763 cites W3017124100 @default.
• W4385851763 cites W3017284665 @default.
• W4385851763 cites W3167151032 @default.
• W4385851763 cites W4240717470 @default.
• W4385851763 cites W65804857 @default.
• W4385851763 doi "https://doi.org/10.1021/acs.inorgchem.3c01891" @default.
• W4385851763 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37584949" @default.
• W4385851763 hasPublicationYear "2023" @default.
• W4385851763 type Work @default.
• W4385851763 citedByCount "0" @default.
• W4385851763 crossrefType "journal-article" @default.
• W4385851763 hasAuthorship W4385851763A5006748375 @default.
• W4385851763 hasAuthorship W4385851763A5020194359 @default.
• W4385851763 hasAuthorship W4385851763A5022160059 @default.
• W4385851763 hasAuthorship W4385851763A5038916444 @default.
• W4385851763 hasAuthorship W4385851763A5048379858 @default.
• W4385851763 hasAuthorship W4385851763A5056912735 @default.
• W4385851763 hasAuthorship W4385851763A5078130910 @default.
• W4385851763 hasAuthorship W4385851763A5080750465 @default.
• W4385851763 hasConcept C112887158 @default.

• next