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- W4385852422 abstract "Abstract Herein, we report a cascade strategy towards 9‐amino‐10‐alkynylphenanthrenes, which involves copper(I)‐catalyzed reactions of 2’‐cyano‐biaryl‐2‐aldehyde N ‐tosylhydrazones and terminal alkynes in a one‐pot manner. In addition, the obtained 9‐amino‐10‐alkynylphenanthrenes could be engaged as π‐extending building blocks in the synthesis of 9 H ‐ dibenzo[3,4:5,6]borinino[1,2‐ b ]phenanthro‐[9,10‐ e ][1,2]azaborinine (BNTBA), a new‐type BN‐embedded PACs, which shows the different properties compared with its all‐carbon analogue tribenzo[ f , k , m ]tetraphene (TBA). The present synthetic method starts from easily available commercial substrates and provides a practical way for the syntheses of highly functionalized phenanthrenes and π‐extension BN‐embedded PACs." @default.
- W4385852422 created "2023-08-17" @default.
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- W4385852422 creator A5088457652 @default.
- W4385852422 date "2023-08-29" @default.
- W4385852422 modified "2023-10-18" @default.
- W4385852422 title "Copper(I)‐Catalyzed Reactions of 2’‐Cyano‐biaryl‐2‐aldehyde <i>N</i>‐Tosylhydrazones with Terminal Alkynes: An Approach towards 9‐Amino‐10‐alkynylphenanthrene Modules" @default.
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- W4385852422 doi "https://doi.org/10.1002/adsc.202300682" @default.
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